157794-12-2

Upstream product

• 58341-63-2 methyl 2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside 
• 76419-48-2 methyl 4,6-O-benzylidene-3-O-benzyl-α-D-glucopyranoside 
• 157794-06-4 2,6-anhydro-1,3,4-tri-O-benzyl-5-O-[tert-butyl(dimethyl)silyl]-7,8,9-trideoxy-D-glycerol-L-gulo-non-8-enitol 
• 157794-05-3 (2R,3S,4R,5R,6R)-2-Allyl-3-allyloxy-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran 
• 157903-83-8 methyl 2-O-allyl-3-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 157794-07-5 (E)-4-[(2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-but-2-enoic acid methyl ester 
• 157794-10-0 (2R,3S)-3-[(2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-oxirane-2-carbaldehyde 
• 157903-84-9 3-(3,4,6-tri-O-benzyl-α-D-glucopyranosyl)-1-propene 
• 100-39-0 benzyl bromide 
• 58341-62-1 methyl 2-O-allyl-3-O-benzyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

Synthesis and Stereochemical Confirmation of the cis-Fused L/M and N/O Ring Systems of Maitotoxin

Stereocontrolled synthesis of cis-fused 1,6-dioxadecalin system 1, which corresponds to the L/M and N/O rings of maitotoxin, was accomplished.Comparison of its (1)H and (13)C NMR data with those of the natural toxin established the earlier stereochemical