58341-63-2

Basic information

• Product Name: methyl 2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside
• Synonyms: methyl 2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside
• CAS NO: 58341-63-2
• Molecular Weight: 504.623
• Mol File: 58341-63-2.mol

Chemical Properties

• CAS DataBase Reference: methyl 2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside(58341-63-2)
• EPA Substance Registry System: methyl 2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside(58341-63-2)

Safety Data

• Hazardous Substances Data: 58341-63-2(Hazardous Substances Data)

Upstream product

• 58341-62-1 methyl 2-O-allyl-3-O-benzyl-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 189144-35-2 methyl 3-O-benzyl-4,6-O-benzylidene-2-O-(4-toluenesulfonyl)-α-D-glucopyranoside 
• 157903-83-8 methyl 2-O-allyl-3-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 76419-48-2 methyl 4,6-O-benzylidene-3-O-benzyl-α-D-glucopyranoside 
• 20672-67-7 (2S,3R,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-methoxy-tetrahydro-pyran-3-ol 
• 106-95-6 allyl bromide 

Downstream Products

• 112289-17-5 benzyl 2-O-(2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranosyl)-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 112289-15-3 benzyl 2-O-(2-O-allyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 112468-78-7 benzyl O-(3,4,6-tri-O-acetyl-2-O-allyl-α-D-glucopyranosyl)-(1->2)-O-(3,4,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 112289-10-8 O-(2-O-allyl-α-D-glucopyranosyl)-(1->2)-O-(3,4,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-β-D-glucopyanoside 
• 112289-16-4 benzyl 3,4,6-tri-O-benzyl-2-O-(3,4,6-tri-O-benzyl-α-D-glucopyranosyl)-β-D-glucopyranoside 
• 112346-24-4 2-O-allyl-3,4,6-tri-O-benzyl-1-O-p-nitrobenzoyl-α-D-glucopyranose 
• 112289-18-6 2-O-allyl-3,4,6-tri-O-benzyl-1-O-(N-methylacetamidoyl)-β-D-glucopyranose 
• 112289-19-7 2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranosyl bromide 
• 112346-23-3 2-O-allyl-3,4,6-tri-O-benzyl-α-D-glucopyranosyl chloride 
• 157794-07-5 (E)-4-[(2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-but-2-enoic acid methyl ester 
• 157794-10-0 (2R,3S)-3-[(2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl]-oxirane-2-carbaldehyde 
• 157794-06-4 2,6-anhydro-1,3,4-tri-O-benzyl-5-O-[tert-butyl(dimethyl)silyl]-7,8,9-trideoxy-D-glycerol-L-gulo-non-8-enitol 
• 157794-12-2 (2R,3S,4aR,6R,7R,8S,8aS)-7,8-Bis-benzyloxy-6-benzyloxymethyl-2-vinyl-octahydro-pyrano[3,2-b]pyran-3-ol 
• 157903-84-9 3-(3,4,6-tri-O-benzyl-α-D-glucopyranosyl)-1-propene 

Relevant articles and documents

Synthesis of kojidextrins and their protein conjugates. Incidence of steric mismatch in oligosaccharide synthesis

Kojidextrins are biologically important oligosaccharides that are involved in many physiological processes including protein glycosylation and bacterial growth. As part of our project to explore the role kojidextrins may play in bacterial pathogenesis, here we report synthetic routes to kojibiose (54), -triose (58), -tetraose (64), and -pentaose (69) equipped with α-linked (hydrazinocarbonyl)pentyl aglycon, using linear and convergent strategies. In the search for a rapid convergent strategy for the construction of extended kojidextrins, four kojibiose donors (1-4) were synthesized that contain acyl- and ether-type protecting groups in various ratios. These were tested to probe the influence of diverse protecting group assemblies on their glycosyl donor ability. Attempted condensation of these donors with kojitriose and -tetraose acceptors failed to give the desired products apparently because of steric mismatch between the donor and the acceptor moieties. A one-pot procedure was developed for the covalent attachment of the synthetic saccharides through their hydrazido group to human serum albumin (HSA) using Tietze's squarate method to give neoglycoproteins containing up to 28 saccharide units per HSA.

Synthesis and Stereochemical Confirmation of the cis-Fused L/M and N/O Ring Systems of Maitotoxin

Stereocontrolled synthesis of cis-fused 1,6-dioxadecalin system 1, which corresponds to the L/M and N/O rings of maitotoxin, was accomplished.Comparison of its (1)H and (13)C NMR data with those of the natural toxin established the earlier stereochemical

SYNTHESIS OF KOJITETRAOSE AND KOJIPENTAOSE

Kojitriose 2)-α-D-Glcp-(1->2)-D-Glcp>, kojitetraose, and kojipentaose have been synthesised by silver perchlorate-promoted Koenigs-Knorr type condensation, using 3,4,6-tri-O-acetyl-2-O-allyl-β-D-glucopyranosyl chloride and hepta-O-acetyl-β-k