1580003-16-2Relevant academic research and scientific papers
No photocatalyst required-versatile, visible light mediated transformations with polyhalomethanes
Franz, Johannes F.,Kraus, Wolfgang B.,Zeitler, Kirsten
supporting information, p. 8280 - 8283 (2015/05/13)
A visible light mediated, but photocatalyst-free method for the oxidative α-CH functionalization of tertiary amines with a broad scope of carbon- and heteroatom nucleophiles using polyhalomethanes has been developed. In addition, the pivotal visible light
Direct sp3 C-H acroleination of N-aryl-tetrahydroisoquinolines by merging photoredox catalysis with nucleophilic catalysis
Feng, Zhu-Jia,Xuan, Jun,Xia, Xu-Dong,Ding, Wei,Guo, Wei,Chen, Jia-Rong,Zou, You-Qua,Lu, Liang-Qiu,Xiao, Wen-Jing
supporting information, p. 2037 - 2040 (2014/03/21)
Sequence catalysis merging photoredox catalysis (PC) and nucleophilic catalysis (NC) has been realized for the direct sp3 C-H acroleination of N-aryl-tetrahydroisoquinoline (THIQ). The reaction was performed under very mild conditions and afforded products in 50-91% yields. A catalytic asymmetric variant was proved to be successful with moderate enantioselectivities (up to 83 : 17 er).
