15813-24-8

Basic information

• Product Name: 2-Propenoic acid, 2-bromo-3-phenyl-, (2Z)-
• CAS NO: 15813-24-8
• Molecular Formula: C9H7BrO2
• Molecular Weight: 227.057
• Mol File: 15813-24-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-bromo-3-phenyl-, (2Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-bromo-3-phenyl-, (2Z)-(15813-24-8)
• EPA Substance Registry System: 2-Propenoic acid, 2-bromo-3-phenyl-, (2Z)-(15813-24-8)

Safety Data

• Hazardous Substances Data: 15813-24-8(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 15894-30-1 (E)-2-Bromo-3-phenyl-acrylic acid 
• 628-13-7 pyridine hydrochloride 
• 6286-30-2 2,3-dibromo-3-phenylpropanoic acid 
• 67-56-1 methanol 
• 19522-37-3 (E)-1-bromo-1-cyano-2-phenylethene 
• 861346-09-0 2,2,3-tribromo-3-phenyl-propionic acid 
• 64-19-7 acetic acid 
• 108-86-1 bromobenzene 
• 637-44-5 phenylpropyolic acid 
• 10035-10-6 hydrogen bromide 
• 108-88-3 toluene 
• 71-43-2 benzene 
• 67-66-3 chloroform 

Downstream Products

• 21788-36-3 (Z)-methyl 2-bromo-3-phenylacrylate 
• 59106-33-1 (Z)-ethyl 2-bromo-3-phenylprop-2-enoate 
• 861346-09-0 2,2,3-tribromo-3-phenyl-propionic acid 
• 140-10-3 (E)-3-phenylacrylic acid 
• 15894-30-1 (E)-2-Bromo-3-phenyl-acrylic acid 
• 5594-32-1 α-bromo-trans-cinnamoyl chloride 
• 42393-45-3 (Z)-2-bromo-3-(4-nitro-phenyl)-acrylic acid 
• 51417-60-8 α-bromo-trans-cinnamic acid-anhydride 
• 6286-30-2 erythro-2,3-dibromo-3-phenylpropanoic acid 
• 637-44-5 phenylpropyolic acid 
• 43091-40-3 5-methyl-2-phenyl-2,3-dihydro-thiazolo[3,2-a]pyridinylium; bromide 
• 6286-30-2 2,3-dibromo-3-phenylpropanoic acid 
• 103-64-0 bromostyrene 
• 122-78-1 phenylacetaldehyde 

Relevant articles and documents

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Cu/CuxOyNPs architectured COF: a recyclable catalyst for the synthesis of oxazolidinedioneviaatmospheric cyclizative CO2utilization

The present study describes the favourable construction of a crystalline covalent organic framework (COF) with exceptional surface area, tunable pore size and huge CO2capture efficiency to facilitate a novel multicomponent cyclization by introducing CO2into extremely reactive organic skeletons. In the presence of a catalytic Cu/CuxOyNP-loaded COF, several 2-bromo-3-alkylacrylic acids combined with several amine derivatives and CO2(0.1 MPa) are converted to the desired oxazolidinediones in excellent yields (up to 96%) under alkali-free conditions and ambient temperature.

Ru-catalyzed highly chemo- and enantioselective hydrogenation of γ-halo-γ,δ-unsaturated-β-keto esters under neutral conditions

Finely-tuned ruthenium-catalyzed highly chemoselective and enantioselective hydrogenation of γ-halo-γ,δ-unsaturated-β-keto esters at the carbonyl group was achieved under neutral reaction conditions (ee up to 97%). Both olefin and alkenyl halogen moieties, which are labile under hydrogenation conditions, remained untouched during the reaction.

Fe(0)-mediated synthesis of tri- and tetra-substituted olefins from carbonyls: An environmentally friendly alternative to Cr(II)

Fe(0) was investigated as a cost-effective, environmentally friendly alternative to Cr(II) for the olefination of carbonyls by activated polyhalides. In many instances, Fe(0) was equivalent or superior to Cr(II). Notably, Fe(0), but not Cr(II), proved com