158309-73-0Relevant academic research and scientific papers
Reactions of thioesters of phosphorus acids with cationic complexes of manganese
Sinyashin, Oleg,Milyukov, Vasily,Zverev, Alexandr,Plyamovatyi, Alexandr,Mukhamadeeva, Raviya,Batyeva, Elvira,Ginzburg, Allan,Sokolov, Vyacheslav
, p. 137 - 140 (1996)
The thioesters of P(III) acids react with [Cp(CO)2Mn(NO)]+ by substituting one CO-group with formation of a stable cationic products with a Mn-P bond. Fourier transform infrared spectroscopy and a special program were used for the real-time monitoring of the mechanistic path of the reaction of S-ethyl-N,N-tetraethyldiamidothiophosphite with [Cp(CO)2Mn(NO)]- BF4+. The formation of a few intermediates is described.
DERIVATIVES OF P(III) THIO ACIDS IN REACTIONS WITH CERTAIN CYCLOPENTADIENYL MANGANESE COMPLEXES
Sinyashin, O. G.,Gorshunov, I. Yu.,Milyukov, V. A.,Batyeva, E. S.,Ginzburg, A. G.,Sokolov, V. I.
, p. 226 - 230 (2007/10/02)
Reactions of cymanthrene and its derivatives with thio esters, O,S-esters, amidothioesters of P(III) acids and thiophosphines were studied.The reactions were found to proceed by several ways: the formation of P-coordinated complexes, which are in essence new cymanthrene derivatives, and the formation of stable organometallic radicals with an Mn-S bond.
