Reactions of thioesters of phosphorus acids with cationic complexes of manganese

Article abstract of DOI:10.1080/10426509608545109

The thioesters of P(III) acids react with [Cp(CO)₂Mn(NO)]⁺ by substituting one CO-group with formation of a stable cationic products with a Mn-P bond. Fourier transform infrared spectroscopy and a special program were used for the real-time monitoring of the mechanistic path of the reaction of S-ethyl-N,N-tetraethyldiamidothiophosphite with [Cp(CO)₂Mn(NO)]^- BF₄⁺. The formation of a few intermediates is described.

Full text of DOI:10.1080/10426509608545109

This article was downloaded by: [University of Bristol]
On: 26 January 2015, At: 08:48
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK
Phosphorus, Sulfur, and Silicon and
the Related Elements
Publication details, including instructions for authors and
subscription information:
http://www.tandfonline.com/loi/gpss20
Reactions of Thioesters of
Phosphorus Acids with Cationic
Complexes of Manganese
Oleg Sinyashin , Vasily Milyukov , Alexandr Zverev ,
Alexandr Plyamovatyi , Raviya Mukhamadeeva , Elvira
Batyeva , Allan Ginzburg & Vyacheslav Sokolov
a
A.E.Arbuzov Institute of Organic & Physical Chemistry,
Kazan Scientific Center, Russian Academy of Sciences ,
Kazan, Russia
b
A.E.Arbuzov Institute of Organic & Physical Chemistry,
Kazan Scientific Center, Russian Academy of Sciences ,
Kazan, Russia
c
A.E.Arbuzov Institute of Organic & Physical Chemistry,
Kazan Scientific Center, Russian Academy of Sciences ,
Kazan, Russia
d
A.E.Arbuzov Institute of Organic & Physical Chemistry,
Kazan Scientific Center, Russian Academy of Sciences ,
Kazan, Russia
e
A.E.Arbuzov Institute of Organic & Physical Chemistry,
Kazan Scientific Center, Russian Academy of Sciences ,
Kazan, Russia
f
A.E.Arbuzov Institute of Organic & Physical Chemistry,
Kazan Scientific Center, Russian Academy of Sciences ,
Kazan, Russia
g
A.E.Arbuzov Institute of Organic & Physical Chemistry,
Kazan Scientific Center, Russian Academy of Sciences ,
Kazan, Russia
h
A.E.Arbuzov Institute of Organic & Physical Chemistry,
Kazan Scientific Center, Russian Academy of Sciences ,
Kazan, Russia
Published online: 06 Aug 2008.
To cite this article: Oleg Sinyashin , Vasily Milyukov , Alexandr Zverev , Alexandr
Plyamovatyi , Raviya Mukhamadeeva , Elvira Batyeva , Allan Ginzburg & Vyacheslav Sokolov

(1996) Reactions of Thioesters of Phosphorus Acids with Cationic Complexes of Manganese,
Phosphorus, Sulfur, and Silicon and the Related Elements, 109:1-4, 137-140
To link to this article: http://dx.doi.org/10.1080/10426509608545109
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the information
(
&
the “Content”) contained in the publications on our platform. However, Taylor
Francis, our agents, and our licensors make no representations or warranties
whatsoever as to the accuracy, completeness, or suitability for any purpose
of the Content. Any opinions and views expressed in this publication are the
opinions and views of the authors, and are not the views of or endorsed by Taylor
&
Francis. The accuracy of the Content should not be relied upon and should be
independently verified with primary sources of information. Taylor and Francis
shall not be liable for any losses, actions, claims, proceedings, demands, costs,
expenses, damages, and other liabilities whatsoever or howsoever caused arising
directly or indirectly in connection with, in relation to or arising out of the use of
the Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan, sub-
licensing, systematic supply, or distribution in any form to anyone is expressly
forbidden. Terms & Conditions of access and use can be found at http://
www.tandfonline.com/page/terms-and-conditions