1486-37-9Relevant articles and documents
Synthesis and structure of copper(II) phosphonodithioite complexes
Kursheva,Kataeva,Perova,Batyeva,Sinyashin,Freilich
, p. 851 - 855 (2005)
A series of new complexes of CuBr with phosphonodithioites were prepared and characterized by NMR and IR spectroscopy. As shown by single crystal X-ray diffraction, diethyl tert-butylphosphonodithioite forms with CuBr a tetrameric cubane-like complex with the monodentate coordination of the organophosphorus ligand via the P atom.
INTERACTION OF DISULFIDES AND SULFENYLCHLORIDES WITH C-N,N-DIALKYLAMINOSUBSTITUTED PHOSPHAALKENES
Ionkin, A. S.,Nikolaeva, N. V.,Nekhoroshkov, V. M.,Efremov, Yu. Ya.,Arbuzov, B. A.
, p. 361 - 365 (2007/10/02)
Interaction of dialkyl disulfides with C-N,N-dimethylaminomethylene-P-phenylphosphine 1a results in the complete cleavage of the P=C double bond and formation of S,S-dialkylphenyldithiophosphonites.Ethyl sulfenylchloride undergoes dehydrochlorination by 1a, while phenyl sulfenylchloride cleaves the P=C bond in C-N,N-dialkylaminosubstituted phosphaalkenes with the predominant formation of either PhP(SPh)2 6 or PhP(SPh)Cl 7 depending on the phosphaalkene used and reaction conditions. Key words: C-(N,N-dialkylamino) substituted phosphaalkenes; disulfides; sulfenylchlorides.
