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1583260-63-2

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1583260-63-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1583260-63-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,5,8,3,2,6 and 0 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1583260-63:
(9*1)+(8*5)+(7*8)+(6*3)+(5*2)+(4*6)+(3*0)+(2*6)+(1*3)=172
172 % 10 = 2
So 1583260-63-2 is a valid CAS Registry Number.

1583260-63-2Relevant articles and documents

Synthesis, characterization and catalytic activity of new aminomethyldiphosphine-Pd(II) complexes for Suzuki cross-coupling reaction

Keles, Mustafa,Yilmaz, Mustafa Kemal

, p. 91 - 94 (2014)

A new range of CF3-substituted aminomethyldiphosphine (P - C - N) ligands ((C6H5)2PCH2) 2NR (R = - C6H4(2-CF3) (1), - C 6H4(3-CF3) (1b) has been synthesized from 2-(trifluoromethyl)aniline and 3-(trifluoromethyl)aniline with diphenylphosphine. The aminomethyldiphosphine ligands were reacted with Pd(cod)Cl2 to give corresponding metal complexes, PdLCl2 (2a, 2b). The aminomethyldiphosphine-palladium compounds were characterized by utilizing several methods including NMR (1H, 13C, 31P) and elemental analysis. These compounds were used as catalysts in Suzuki cross-coupling reaction of aryl chlorides and bromides. The effect of base was also investigated in this current project. CF3-substituted aminomethyldiphosphine-palladium complexes were found to be efficient catalysts in Suzuki cross-coupling reaction of activated and deactivated aryl boronic acids.

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