Applied Organometallic Chemistry p. 91 - 94 (2014)
Update date:2022-08-05
Topics:
Keles, Mustafa
Yilmaz, Mustafa Kemal
A new range of CF3-substituted aminomethyldiphosphine (P - C - N) ligands ((C6H5)2PCH2) 2NR (R = - C6H4(2-CF3) (1), - C 6H4(3-CF3) (1b) has been synthesized from 2-(trifluoromethyl)aniline and 3-(trifluoromethyl)aniline with diphenylphosphine. The aminomethyldiphosphine ligands were reacted with Pd(cod)Cl2 to give corresponding metal complexes, PdLCl2 (2a, 2b). The aminomethyldiphosphine-palladium compounds were characterized by utilizing several methods including NMR (1H, 13C, 31P) and elemental analysis. These compounds were used as catalysts in Suzuki cross-coupling reaction of aryl chlorides and bromides. The effect of base was also investigated in this current project. CF3-substituted aminomethyldiphosphine-palladium complexes were found to be efficient catalysts in Suzuki cross-coupling reaction of activated and deactivated aryl boronic acids.
View MoreYurui(Shanghai)Chemical Co.,Ltd
Contact:0086 21-50456736
Address:No.3188 Xiupu Road,Shanghai
Shanghai Sinofluoro Scientific Co., Ltd
Contact:+86-21-64279360
Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
Hunan Shineway Enterprise Co., Ltd.
Contact:+86-731-86303875
Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
website:http://www.shtopchem.com/
Contact:0086-0576-87776998
Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
Contact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Doi:10.1016/j.tet.2014.02.038
(2014)Doi:10.1016/j.tetlet.2014.05.114
(2014)Doi:10.1021/jo00096a001
(1994)Doi:10.1016/0968-0896(96)00141-1
(1996)Doi:10.1002/cmdc.201300420
(2014)Doi:10.1134/S1070428014020225
(2014)