158478-40-1

Upstream product

• 37464-87-2 (5-bromopent-1-enyl)benzene 
• 107-11-9 1-amino-2-propene 
• 1449213-87-9 C₁₄H₁₇NO 
• 28525-69-1 (4E)-5-phenyl-4-pentenoic acid 
• 22768-07-6 (E)-ethyl 5-phenylpent-4-enoate 
• 13159-16-5 5-phenyl-4-penten-1-ol 

Downstream Products

• 144220-38-2 trans-N-allyl-N-(benzenesulfenyl)-5-phenylpent-4-enylamine 
• 99896-08-9 8-phenylindolizidine 

Relevant academic research and scientific papers

Catalytic asymmetric synthesis of (S)-laudanosine by hydroamination

Lithium amide-chiral bisoxazoline-catalyzed asymmetric intramolecular hydroamination was examined with respect to the structural variants of starting aminoalkenes. Substituents on the nitrogen and olefin of aminoalkenes were found to be important factors affecting reaction efficiency as well as enentioselectivity in the production of chiral tetrahydroisoquinolines and isoindolines. The catalytic asymmetric total synthesis of (S)-laudanosine highlights the utility of the asymmetric hydroamination.

Facile Generation of Alkyl, Aminyl, and Alkoxy Radicals from Se-Phenyl Benzoselenohydroximate Derivatives

Se-Phenyl benzoselenohydroximate derivatives, which are prepared from stable and readily available Se-phenyl benzoselenohydroximate, are useful radical precursors for the generation of alkyl, aminyl, and alkoxy radicals.

Synthesis of pyrrolizidines using aminyl radicals generated from sulfenamide precursors

Tandem radical cyclisations of aminyl radicals generated from sulfenamide precursors have been used for the synthesis of pyrrolizidines and other polycyclic nitrogen heterocycles. The aminyl radicals are generated by reaction between sulfenamide precursor