15876-34-3Relevant academic research and scientific papers
Highly efficient solvent-free acetylation of alcohols with acetic anhydride catalyzed by recyclable sulfonic acid catalyst (SBA-15-Ph-Pr-SO3H)- An environmentally benign method
Zareyee, Daryoush,Ghadikolaee, Abdollah Razaghi,Khalilzadeh, Mohammad A.
, p. 464 - 468 (2012)
The catalytic activity of highly thermal stable, hydrophobic, and complete heterogeneous propylsulfonic acid functionalized nanostructured SBA-15 for excellent acetylation of alcohols and phenols with acetic anhydride at ambient temperature in solvent-free conditions was examined under environmentally benign reaction conditions. The salient features of this protocol are the absence of solvent, a green experimental procedure, and simple reusability of the catalyst (at least five reaction cycles).
Solvent-free acetylation and tetrahydropyranylation of alcohols catalyzed by recyclable sulfonated ordered nanostructured carbon
Zareyee, Daryoush,Alizadeh, Parastoo,Ghandali, Mohammad S.,Khalilzadeh, Mohammad A.
, p. 713 - 721 (2013/07/26)
Rapid and practical green acetylation and tetrahydropyranylation routes of structurally diverse alcohols and phenols were applied under solvent-free reaction conditions providing excellent yields, using catalytic amounts of environmentally friendly sulfonated ordered nanoporous carbon (CMK-5-SO 3H). Non-toxic nature of the catalyst, its easy handling, recovery and reusability, and the absence of any solvent characterize the presented procedures as efficient methods. These procedures provide methods for the separation of the product by simple filtration.
Meerwein-Ponndorf-Verley-type reductive acetylation of carbonyl compounds to acetates by lanthanide complexes in the presence of isopropenyl acetate
Nakano, Yasushi,Sakaguchi, Satoshi,Ishii, Yasutaka
, p. 1565 - 1569 (2007/10/03)
Meerwein-Ponndorf-Verley-type reductive acetylation of carbonyl compounds to acetates was successfully carried out in the presence of isopropenyl acetate under the influence of a catalytic amount of Ln(O(i)Pr)3 at room temperature. Various carbonyl compounds were converted into the corresponding acetates in fair to good yields. (C) 2000 Elsevier Science Ltd.
Effect of Solvent on Lipase-Catalyzed Transesterification in Organic Media
Nakamura, Kaoru,Kinoshita, Masamichi,Ohno, Atsuyoshi
, p. 4681 - 4690 (2007/10/02)
Lipase-catalyzed transesterifications of cis- and trans-4-methylcyclohexanols with vinyl acetate in various organic solvents have been studied, and the effect of solvent on activity and stereoselectivity of lipase has been investigated.Initial rate of the reaction increases with the increase in hydrophobicity of the solvent excerting a good correlation with logP', a corrected index of logP.However, since the stereoselectivity is also affected by molecularity of the solvent, the correlation between stereoselectivity factor, γ, and log P' is poor.The solvent effect on the stereoselectivity has been correlated with excellent linearity by the aid of two-parameter relationship; γ=a(εr-1)/(2εr+1)+bVm, where εr and Vm denote dielectric constant and molar volume of the solvent, respectively.
