OXIDATION OF cis-DIALKYLCOBALT(III) COMPLEXES BY OXIGEN. ACTIVATION OF OXIGEN BY PERCHLORIC ACID

DOI: 10.1246/cl.1986.1

Source and publish data:

Chemistry Letters p. 1 - 4 (1986)

Update date:2022-08-02

Topics:

Authors:

Fukuzumi, Shunichi

Ishikawa, Kunio

Tanaka, Toshio

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Article abstract of DOI:10.1246/cl.1986.1

The effects of protons on the reactions of cis-dialkylcobalt(III) complexes, cis-ClO4 (R = Me, Et, PhCH2; bpy = 2,2'-bipyridine), with oxigen are reported.Oxigen is shown to be activated in the presence of perchloric acid by forming hydroperoxonium ion which has a much stronger oxidizing ability than oxigen.

Full text of DOI:10.1246/cl.1986.1

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