159085-28-6Relevant articles and documents
Synthesis of triazene-substituted homoconjugated push-pull chromophores by formal [2?+?2] cycloadditions
Erden, Kübra,Sava?, ?pek,Dengiz, Cagatay
, p. 1982 - 1985 (2019)
1-(4-Ethynylphenyl)-3,3-dialkyltriaz-1-enes, well-known building blocks for branched dendrimer syntheses, were utilized as a new type of electron-donor component in formal [2 + 2] cycloadditions. The click-type, atom-economic reactions proceed efficiently
Suzuki-Miyaura cross-coupling reaction of 1-aryltriazenes with arylboronic acids catalyzed by a recyclable polymer-supported N-heterocyclic carbene-palladium complex catalyst
Nan, Guangming,Ren, Fang,Luo, Meiming
experimental part, (2010/11/21)
The Suzuki-Miyaura cross-coupling reaction of 1-aryltriazenes with arylboronic acids catalyzed by a recyclable polymer-supported Pd-NHC complex catalyst has been realized for the first time. The polymer-supported catalyst can be re-used several times still retaining high activity for this transformation. Various aryltriazenes were investigated as electrophilic substrates at room temperature to give biaryls in good to excellent yields and showed good chemoselectivity over aryl halides in the reactions.