159163-67-4Relevant academic research and scientific papers
Structural Elucidation of Selective Solvatochromism in a Responsive-at-Metal Cyclometalated Platinum(II) Complex
Andrews, Ryan J.,Carta, Veronica,Chaudhry, Mohammad T.,MacLachlan, Mark. J.,Soto, Miguel A.
supporting information, p. 10348 - 10352 (2020/05/25)
We report the synthesis, characterization, and spectroscopic investigations of a new responsive-at-metal cyclometalated platinum(II) complex. With mild chemical oxidants and reductants, it was possible to obtain the same complex in three different oxidati
Allosteric Interaction of Metal Ions with Saccharides in a Crowned Diboronic Acid
Deng, Gang,James, Tony D.,Shinkai, Seiji
, p. 4567 - 4572 (2007/10/02)
A diboronic acid saccharide (covalent) receptor site and a crown metal ion (electrostatic) receptor site are succesfully coupled in an allosteric system.The binding of monosaccharides with 2b as intramolecular 1:1 complexes was monitored by circular dichroism (CD).Added calcium perchlorate reduces the binding of the 1:1 saccharide complexes as followed by a decrease in the CD activity.This is a novel allosteric system which mimics the action of the Na+/D-glucose cotransport protein in nature.
