159454-76-9

Basic information

• Product Name: C₁₈H₂₀N₄O₂
• Synonyms: C₁₈H₂₀N₄O₂
• CAS NO: 159454-76-9
• Molecular Weight: 324.382
• Mol File: 159454-76-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₁₈H₂₀N₄O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₂₀N₄O₂(159454-76-9)
• EPA Substance Registry System: C₁₈H₂₀N₄O₂(159454-76-9)

Safety Data

• Hazardous Substances Data: 159454-76-9(Hazardous Substances Data)

Upstream product

• 20439-47-8 (1R,2R)-1,2-diaminocyclohexane 
• 20260-53-1 pyridine-3-carbonyl chloride hydrochloride 
• 10400-19-8 3-pyridinecarbonyl chloride 

Relevant articles and documents

Antarafacial hydride transfer in a new chiral NADH model with C2symmetry

A C2-symmetric macrocyclic NAD+/NADH-model, 1, in which hydride transfer occurs in an antarafacial way, has been prepared. On reduction of methyl benzoylformate with 1, methyl mandelate is formed in 95% ee.

Zinc meso-Tetraphenylporphyrin as Shift Reagent for NADH-Models

By the use of zinc meso-tetraphenylporphyrin as a shift reagent the conformations of two new NADH-models have been determined.Induced 1H-NMR shifts up to five ppm have been observed.The conformations determined in this study are consistent with theoretical calculations and NOE-measurements.It has been proven that zinc, which is a so-catalyst in the reduction of activated carbonyl compounds with NADH-models, coordinates to the oxygen of the amide groups in two of our model compounds.