Antarafacial hydride transfer in a new chiral NADH model with C2symmetry

DOI: 10.1016/S0040-4039(00)91724-6

Source and publish data:

Tetrahedron Letters p. 1751 - 1754 (1992)

Update date:2022-07-30

Topics:

Authors:

Skog, Klas

Wennerstroem, Olof

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Article abstract of DOI:10.1016/S0040-4039(00)91724-6

A C₂-symmetric macrocyclic NAD⁺/NADH-model, 1, in which hydride transfer occurs in an antarafacial way, has been prepared. On reduction of methyl benzoylformate with 1, methyl mandelate is formed in 95% ee.

Full text of DOI:10.1016/S0040-4039(00)91724-6

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