15949-79-8Relevant academic research and scientific papers
Electrophilic chloro(ω-alkoxy)lation of alkenes employing 1-chloro-1,2-benziodoxol-3-one: Facile synthesis of β-chloroethers
Jia, Yimin,Chen, Long,Zhang, Huaibin,Zheng, Ying,Jiang, Zhong-Xing,Yang, Zhigang
, p. 7203 - 7213 (2018/10/24)
A four-component reaction for electrophilic chloro(ω-alkoxy)lation of alkenes has been described. The stable chloro-iodine(iii) reagent and SOCl2 were used as electrophilic and nucleophilic chlorine sources, respectively. This approach provides a straightforward way to synthesize various useful β-chloro ω-chloroalkyl ethers from a wide range of alkenes, including electron-deficient, aromatic and unactivated alkenes. The synthetic applications of this approach were also explored in some useful transformations.
Cohalogenation of Alkenes: A New Base Induced Fragmentation Reaction of β,δ'-Dihalogenated Ethers to Oxiran and Butadiene. Indirect Oxygen Atom Transfer from THF
Dulcere, Jean-Pierre,Rodriguez, Jean
, p. 1893 - 1898 (2007/10/02)
A new base induced fragmentation reaction of β,δ'-dihalogenated ethers leading to oxiran and butadiene is described.
REACTION OF PLEFINS WITH SULFURYL CHLORIDE AND CYCLIC RTHERS: AN EFFICIENT SYNTHESIS OF α-CHLOROALKYL ω-CHLOROALKYL ETHERS
Joseph, Sajan P.,Keshavamurthy, K. S.,Dhar, D. N.
, p. 889 - 896 (2007/10/02)
Olefins react with sulfuryl chloride in presence of cyclic ethers to form the corresponding α-chloroalkyl ω-chloroalkyl ethers.
