159496-97-6

Basic information

• Product Name: 1H-Indene-1-carboxaldehyde, 2,3-dihydro-, (+)- (9CI)
• Synonyms: indan-1-carbaldehyde
• CAS NO: 159496-97-6
• Molecular Formula: C₁₀H₁₀O
• Molecular Weight: 146.19
• Product Categories: ALDEHYDE
• Mol File: 159496-97-6.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 247.3±19.0 °C(Predicted)
• Appearance: /
• Density: 1.168±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1H-Indene-1-carboxaldehyde, 2,3-dihydro-, (+)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indene-1-carboxaldehyde, 2,3-dihydro-, (+)- (9CI)(159496-97-6)
• EPA Substance Registry System: 1H-Indene-1-carboxaldehyde, 2,3-dihydro-, (+)- (9CI)(159496-97-6)

Safety Data

• Hazardous Substances Data: 159496-97-6(Hazardous Substances Data)

Upstream product

• 26452-97-1 1-cyanoindane 
• 201230-82-2 carbon monoxide 
• 95-13-6 1-indene 
• 105-39-5 chloroacetic acid ethyl ester 
• 83-33-0 inden-1-one 
• 90794-28-8 2-iodo-1,2,3,4-tetrahydro-[1]naphthol 
• 60-29-7 diethyl ether 
• 112951-05-0 C₁₁H₁₀O₃ 
• 67197-73-3 Indan-1-spiro-2'-oxiran-3'-carbonsaeure-aethylester 
• 39834-40-7 trans-2-bromo-1,2,3,4-tetrahydronaphthalen-1-ol 
• 4009-98-7 (methoxymethyl)triphenylphosphonium chloride 
• 447-53-0 1,2-Dihydronaphthalene 
• 132884-23-2 methyl indan-1-spiro-2'-oxirane-3'-carboxylate 
• 35275-62-8 1-chloroindane 

Downstream Products

• 14381-42-1 Indan-1-carboxylic acid 
• 1092492-05-1 (R)-1-phenyl-2,3-dihydro-1H-indene-1-carbaldehyde 
• 132884-12-9 (1R,αS;1S,αR)-1-(α-methoxybenzyl)indan 
• 132884-12-9 (1S,αS;1R,αR)-1-(α-methoxybenzyl)indan 
• 496-11-7 INDANE 
• 95-13-6 1-indene 
• 146393-32-0 1-indanylphenylcarbinol 

Relevant articles and documents

NOVEL RUTHENIUM COMPLEXES, METHODS OF THEIR PREPARATION AND APPLICATION THEREOF IN OLEFIN CROSS METATHESIS

The invention relates to novel ruthenium complexes of general formula 4 in which the substituents are defined herein. The invention relates also to methods for preparing such compounds and use thereof as catalysts and/or (pre)catalysts in olefin cross metathesis.

Metal-free synthesis of indanes by iodine(iii)-mediated ring contraction of 1,2-dihydronaphthalenes

A metal-free protocol was developed to synthesize indanes by ring contraction of 1,2-dihydronaphthalenes promoted by PhI(OH)OTs (HTIB or Koser's reagent). This oxidative rearrangement can be performed in several solvents (MeOH, CH3CN, 2,2,2-trifluoroethanol (TFE), 1,1,1,3,3,3-hexafluoroisopropanol (HFIP), and a 1:4 mixture of TFE:CH2Cl2) under mild conditions. The ring contraction diastereoselectively gives functionalized trans-1,3-disubstituted indanes, which are difficult to obtain in synthetic organic chemistry. ?2011 Sociedade Brasileira de Qui?mica.

Ring contraction of 1,2-dihydronaphthalenes promoted by thallium(III) in acetonitrile: A diastereoselective approach to indanes

Trans-1,3-Disubstituted indanes are conveniently accessed by a stereoselective ring contraction of 1,2-dihydronaphthalenes upon treatment with thallium(III) nitrate (TTN) in acetonitrile. Under these conditions, the oxidative rearrangement of either di- or trisubstituted double bonds is possible. Georg Thieme Verlag Stuttgart.