1595-38-6

Upstream product

• 5651-88-7 phenyl propargyl sulfide 
• 624-65-7 2-propynyl chloride 
• 108-98-5 thiophenol 
• 106-96-7 propargyl bromide 
• 1192-40-1 copper(I) thiophenolate 
• 78-88-6 2,3-Dichloroprop-1-ene 
• 882-33-7 diphenyldisulfane 
• 37605-46-2 (propa-1,2-diene-1-sulfinyl)benzene 
• 13023-53-5 3-phenylsulfanyl-butan-2-one 
• 659-86-9 propargyl iodide 
• 75-77-4 chloro-trimethyl-silane 
• 6212-77-7 1-phenylthio-1-propyne 

Downstream Products

• 10575-06-1 but-1-yn-4-yl phenyl sulfide 
• 134427-79-5 ethyl (2-phenylthio)-2-(trifluoromethyl)-4-pentynoate 
• 6212-77-7 1-phenylthio-1-propyne 
• 144386-78-7 (η1,η3-PhSCHCCH2)Fe2(CO)6 
• 54234-79-6 (R)-(propylsulfinyl)benzene 
• 109120-75-4 phenyl n-propyl sulfoxide 
• 67653-00-3 (+/-)_S-(Z)-1-(phenylsulfinyl)prop-1-ene 

Relevant academic research and scientific papers

Exploiting Substrate Diversity for Preparing Synthetically Valuable Sulfoxides via Asymmetric Hydrogenative Kinetic Resolution

A detailed study is disclosed on the Rh-mediated hydrogenative kinetic resolution of α,β-unsaturated sulfoxides with alkyl and aryl substituents at the α-, E- and Z-positions of the double bond. This stereoselective catalytic methodology has enabled the p

Domino reaction of 2,3-dichloroprop-1-ene with diphenyl disulfide in the system hydrazine hydrate-potassium hydroxide

2,3-Dichloroprop-1-ene reacted with diphenyl disulfide in the system hydrazine hydrate-potassium hydroxide at 30-35 C to give three products: 2-chloro-3-phenylsulfanylprop-1-ene, 1-phenylsulfanylpropadiene, and 1-phenylsulfanylprop-1-yne. Variation of tem

Studies on the regio- and stereoselectivity of halohydroxylation of 1,2-allenyl sulfides or selenides

It was observed that the halohydroxylation of 1,2-allenyl sulfides or selenides with Br2 (CuBr2 or NBS) or I2 and water demonstrated a fairly good regioselectivity (i.e., the C=C bond that is remote from the S or Se atom w

Prototropic rearrangement of 2-propynyl(methyl)amino, 2-propynyloxy, and 2-propynylsulfanyl derivatives of hetarenes under conditions of phase-transfer catalysis: Mechanism and limitations

2-Propynyl derivatives of N-methylaniline, phenol, benzenethiol, 2-pyridinethiol, 2-pyrimidinethiol, and 1,3-benzoxazole-2-thiol were synthesized. Under conditions of phase-transfer catalysis, phenyl 2-propynyl sulfide is converted into allenyl phenyl sul

Rearrangements of 2-Phenylthioethanols with Alkenyl, Alkynyl, Ester, and Other Functionalised Alkyl Substituents at the Migration Origin: Synthesis of γ-Phenylthiocrotonate Esters

The effects of functional groups near the migration origin in and PhS shifts are explored: an α-CO2R group prevents migration, α or β vinyl groups have only steric effects, alkynyl or CO2Et groups encourage rearrangement and provide routes to γ-phenylthio unsaturated esters and ketones.

CINETIQUE ET MECANISME DE LA REACTION DE PROTOTROPIE DES COMPOSIES PROPARGYLIQUES, ALLENIQUES ET PROPYNYLIQUES PORTANT UN HETEROATOME (COLONNE Vb ET VIb)

A detailed kinetic study of the prototropic rearrangement of the system RMCH2-CCHRM-CH=C=CH2RM-CC-CH3 where M=NR, O, S, Se is presented.Using deuterated substrates the nature of the reactive intermediates and, in the case of M=S, the activatio

PHENYLTHIOCOPPER TRIMETHYLPHOSPHITE COMPLEX. A REAGENT FOR THE PREPARATION OF THIOALLENES.

The title complex reacts with propargyl halides and, in situ generated, propargyl mesylates to produce thioallenes in good yields, via an allylic inversion.