1595-40-0

Basic information

• Product Name: phenoxyallene
• Synonyms: phenoxyallene
• CAS NO: 1595-40-0
• Molecular Weight: 132.162
• Mol File: 1595-40-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: phenoxyallene(CAS DataBase Reference)
• NIST Chemistry Reference: phenoxyallene(1595-40-0)
• EPA Substance Registry System: phenoxyallene(1595-40-0)

Safety Data

• Hazardous Substances Data: 1595-40-0(Hazardous Substances Data)

Upstream product

• 766-94-9 vinyl phenyl ether 
• 108-95-2 phenol 
• 139-02-6 sodium phenoxide 
• 13610-02-1 1-phenoxy-2-propyne 

Downstream Products

• 1261351-97-6 3-methylene-2-phenoxy-3,4-dihydro-2H-pyran 
• 263388-36-9 (2S,3S,4S,5R,6R)-2-Allyl-4,5-bis-benzyloxy-6-benzyloxymethyl-3-((R)-1-phenoxy-allyloxy)-tetrahydro-pyran 
• 131168-77-9 1,2,3,4-Tetrakis(carbomethoxy)-5-phenoxymethyl-benzol 
• 68870-46-2 6-phenoxy-3,9-diphenyl-1,7-dioxa-2,8-diaza-spiro[4.4]nona-2,8-diene 
• 68870-45-1 4-(E)-phenoxymethylene-3-phenyl-4,5-dihydro-isoxazole 
• 68870-44-0 4-(Z)-phenoxymethylene-3-phenyl-4,5-dihydro-isoxazole 
• 35121-46-1 5-phenoxymethyl-3-phenyl-isoxazole 
• 68870-63-3 3-(4-chloro-phenyl)-4-(Z)-methoxymethylene-4,5-dihydro-isoxazole 
• 68870-48-4 3,9-bis-(4-chloro-phenyl)-6-phenoxy-1,7-dioxa-2,8-diaza-spiro[4.4]nona-2,8-diene 
• 69054-31-5 3-(4-chloro-phenyl)-4-(E)-phenoxymethylene-4,5-dihydro-isoxazole 
• 68870-47-3 3-(4-chloro-phenyl)-4-(Z)-phenoxymethylene-4,5-dihydro-isoxazole 

Relevant articles and documents

Enantioselective Palladium-Catalyzed Hydrophosphinylation of Allenes with Phosphine Oxides: Access to Chiral Allylic Phosphine Oxides

A Pd-catalyzed hydrophosphinylation of alkyl and aryl-oxyallenes with phosphine oxides has been developed for the efficient and rapid construction of a family of chiral allylic phosphine oxides with a diverse range of functional groups. This methodology was further applied in the facile construction of chiral 2H-chromene and later stage functionalization of cholesterol.

Pd-Catalyzed Hydroamination of Alkoxyallenes with Azole Heterocycles: Examples and Mechanistic Proposal

Palladium-catalyzed regio- and enantioselective addition of azole heterocycles to alkoxyallenes was developed (up to 92% yields and up to 94% ee). DFT calculations suggest a new Pd(0)-driven mechanistic pathway proceeding through protonation of the Pd-coo

Gold(I)-catalyzed hydroindolylation of allenyl ethers

The gold(I)-catalyzed reaction/rearrangement of allenyl ethers has been investigated in the presence of indoles. Either hydroindolylation or alkylation of an indole with the pendant group of allenyl ether has been observed. The reaction outcome seems to b