1596368-67-0Relevant articles and documents
3-(7-Dimethylamino)coumarin N-phenylsemicarbazones in solution and polymer matrices: Tuning their fluorescence via para-phenyl substitution
Cigáň, Marek,Danko, Martin,Donovalová, Jana,Ga?par, Jan,Stankovi?ová, Henrieta,Gáplovsky, Anton,Hrdlovi?, Pavol
, p. 36 - 45 (2014)
The photo-physical properties of five new para-phenyl substituted derivatives of 3-(7-dimethylamino)coumarin N-phenylsemicarbazone with various electron-withdrawing substituents R (RF, Br, CF3, CN or NO 2) in the para-position on the phenyl ring were investigated in solvents and in polymer matrices. Tuning their fluorescent properties via para-substitution is discussed in terms of Twisted Intra-molecular Charge-Transfer (TICT) state formation, specific solute-solvent interactions (hydrogen bonding), fluorescent H-aggregates formation, and the solvent polarity and polymer matrix effects.