15989-90-9Relevant academic research and scientific papers
TfOH promoted reactions of vinyl gem-dichlorocyclopropanes with arenes: access to aryl gem-dichloropentenes
Kazakova, Anna A.,Bogomazova, Anna A.,Iakovenko, Roman O.,Zlotsky, Simon S.,Vasilyev, Aleksander V.
, p. 4210 - 4212 (2016)
The reaction of 1,1-dichloro-2-vinylcyclopropane with arenes under the action of the superacid TfOH afforded 3-aryl-1,1-dichloropent-1-enes (25–43% yield), as the products of cyclopropane ring opening. The reaction of 1,1-dichloro-2-methyl-2-vinylcyclopro
Process for the preparation of geminal diarylalkanes, new geminal diarylalkanes and alk(en)ylated aromatic compounds
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, (2008/06/13)
The invention relates to a new process for the preparation of geminal diarylalkanes of the formula STR1 by Friedel-Crafts alkylation of aromatic compounds with specific aliphatic halogen compounds (addition compounds of CCl4 , to α-olefins), to new geminal diarylalkanes and the aralkyl compounds resulting as intermediates.
