159922-67-5

Usage

Chemical Properties

White powder

InChI:InChI=1/C16H22O7/c1-16(2)22-13-11(8-17)21-15(12(18)14(13)23-16)20-10-6-4-9(19-3)5-7-10/h4-7,11-15,17-18H,8H2,1-3H3/t11-,12-,13+,14-,15-/m1/s1

Upstream product

• 67-64-1 acetone 
• 3150-20-7 4-methoxyphenyl β-D-galactopyranoside 
• 77-76-9 2,2-dimethoxy-propane 
• 2872-65-3 4-methoxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranoside 
• 150-76-5 4-methoxy-phenol 
• 4163-60-4 β-D-galactose peracetate 

Downstream Products

• 212127-28-1 p-methoxyphenyl 3,4-O-isopropylidene-6-O-(1-methoxy-1-methylethyl)-β-D-galactopyranoside 
• 859505-01-4 4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-galactopyranosyl-(1->3)-2,6-di-O-benzyl-β-D-galactopyranoside 
• 159922-50-6 4-methoxyphenyl 2,6-di-O-benzyl-β-D-galactopyranoside 
• 1201011-97-3 4-methoxyphenyl 2,6-di-O-acetyl-3,4-O-isopropylidene-β-D-galactopyranoside 
• 1256157-19-3 4-methoxyphenyl 2-O-benzyl-3,4-O-isopropylidene-α-L-fucopyranosyl-(1->2)-[3-O-acetyl-4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-galactopyranosyl-(1->6)]-3,4-O-isopropylidene-β-D-galactopyranoside 
• 1256157-16-0 4-methoxyphenyl 6-O-tert-butyldimethylsilyl-3,4-O-isopropylidene-β-D-galactopyranoside 
• 1332838-89-7 p-methoxyphenyl 6-O-benzoyl-3,4-O-isopropylidene-β-D-galactopyranoside 
• 1332838-94-4 p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-6-O-benzoyl-β-D-galactopyranoside 
• 1332838-96-6 p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-4-O-acetyl-6-O-benzoyl-β-D-galactopyranoside 
• 1332839-00-5 p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-4-O-acetyl-6-O-benzoyl-3-O-(2,3,4-tri-O-acetyl-α-L-arabinopyranosyl)-β-D-galactopyranoside 
• 1332839-02-7 p-methoxyphenyl 3,4,6-tri-O-acetyl-2-acetamido-2-deoxy-β-D-glucopyranosyl-(1->2)-4-O-acetyl-6-O-benzoyl-3-O-(2,3,4-tri-O-acetyl-α-L-arabinopyranosyl)-β-D-galactopyranoside 
• 1332838-84-2 p-methoxyphenyl 2-acetamido-2-deoxy-β-D-glucopyranosyl-(1->2)-3-O-(α-L-arabinopyranosyl)-β-D-galactopyranoside 
• 1332838-92-2 p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-6-O-benzoyl-3,4-O-isopropylidene-β-D-galactopyranoside 
• 1104513-35-0 p-methoxyphenyl 4-O-acetyl-2,6-di-O-benzyl-β-D-galactopyranoside 

Relevant academic research and scientific papers

Total synthesis of sulfated glycosphingolipid SM1a, a kind of human epithelial carcinoma antigen

A highly efficient and practical total synthesis of the sulfated ganglioside SM1a, a kind of human epithelial carcinoma antigen identified in mammalian kidney, has been accomplished for the first time. The characteristic sequence of SM1a, β-D-Galp-(1→3)-β

Iodine/toluenesulfonic acid: A novel catalyst for isopropylidenation in carbohydrate chemistry

A novel catalyst for O-isopropylidenation of carbohydrates, a mixture of toluenesulfonic acid and iodine, was developed.

Synthesis of a set of sulfated and/or phosphorylated oligosaccharide derivatives from the carbohydrate-protein linkage region of proteoglycans

The synthesis of a set of various sulfoforms and/or phosphoforms as 7-methoxy-2-naphthyl glycosides of β-d-Xylp, β-d-Galp-(1→4)-β-d-Xylp, and β-d-Galp-(1→3)-β-d-Galp-(1→4)-β-d-Xylp, structures encountered in the common carbohydrate-protein linkage region

Synthesis of some blocked di- and trisaccharide derivatives related to the repeating unit of the O-antigen from Shigella dysenteriae type 3 in the form of their glycosides

Starting from D-galactose and D-galactosamine hydrochloride, two new monosaccharide synthons namely 2-(trimethylsilyl)ethyl 4-O-acetyl-2,6-di-O- benzyl-β-D-galactopyranoside 2 and phenyl 3-O-acetyl-4,6-O-benzylidene-2- deoxy-2-phthalimido-1-thio-β-D-galac

Efficient synthesis of two HNK-1 related pentasaccharides

Two pentasaccharides, representative of those found on complex N-glycans, were synthesized for use as potential substrates for sulfotransferases. The synthesis was achieved by the addition of a disaccharide donor β-D-GlcA(1→3)α-D-Gal-trichloroacetimidate

SYNTHESIS OF HUMAN M BLOOD GROUP ANTIGENIC GLYCOPEPTIDE

A first total synthesis of terminal glycoheptapeptide of human glycophorin AM was accomplished by solution phase peptide condensation utilizing the tetrasaccharide-linked amino acid building blocks designed for Fmoc strategy.