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N-(tert-butyloxycarbonyl)glycine {N-benzyl-N-[4-ethoxycarbonyl-oxy-(2E)-buten-1-yl]}amide is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1599423-13-8 Structure
  • Basic information

    1. Product Name: N-(tert-butyloxycarbonyl)glycine {N-benzyl-N-[4-ethoxycarbonyl-oxy-(2E)-buten-1-yl]}amide
    2. Synonyms: N-(tert-butyloxycarbonyl)glycine {N-benzyl-N-[4-ethoxycarbonyl-oxy-(2E)-buten-1-yl]}amide
    3. CAS NO:1599423-13-8
    4. Molecular Formula:
    5. Molecular Weight: 406.479
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1599423-13-8.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: N-(tert-butyloxycarbonyl)glycine {N-benzyl-N-[4-ethoxycarbonyl-oxy-(2E)-buten-1-yl]}amide(CAS DataBase Reference)
    10. NIST Chemistry Reference: N-(tert-butyloxycarbonyl)glycine {N-benzyl-N-[4-ethoxycarbonyl-oxy-(2E)-buten-1-yl]}amide(1599423-13-8)
    11. EPA Substance Registry System: N-(tert-butyloxycarbonyl)glycine {N-benzyl-N-[4-ethoxycarbonyl-oxy-(2E)-buten-1-yl]}amide(1599423-13-8)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1599423-13-8(Hazardous Substances Data)

1599423-13-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1599423-13-8 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,5,9,9,4,2 and 3 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1599423-13:
(9*1)+(8*5)+(7*9)+(6*9)+(5*4)+(4*2)+(3*3)+(2*1)+(1*3)=208
208 % 10 = 8
So 1599423-13-8 is a valid CAS Registry Number.

1599423-13-8Relevant articles and documents

Synthesis of α-Amino-γ-lactams through Pd-Catalzed Intramolecular Allylic Alkylation of Sarcosine Allyl Amides

Thies, Sarah,Kazmaier, Uli

, p. 1695 - 1707 (2015/10/05)

N-Protected amino acid allyl amides with an allylic leaving group can be used as substrates in palladium-catalyzed allylic alkylation. Whereas intermolecular allylations proceed with excellent yields under standard conditions for enolate reactions, the intramolecular version is not a trivial issue. N-Protected glycine amides preferentially form piperidinones through N-allylation, but the corresponding sarcosine derivatives provide γ-lactams in acceptable to good yields in dichloromethane, especially when the corresponding titanium enolates are formed.

Synthesis of α-amino-γ-lactams through Pd-catalzed intramolecular allylic alkylation of sarcosine allyl amides

Thies, Sarah,Kazmaier, Uli

, p. 1695 - 1707 (2014/03/21)

N-Protected amino acid allyl amides with an allylic leaving group can be used as substrates in palladium-catalyzed allylic alkylation. Whereas intermolecular allylations proceed with excellent yields under standard conditions for enolate reactions, the intramolecular version is not a trivial issue. N-Protected glycine amides preferentially form piperidinones through N-allylation, but the corresponding sarcosine derivatives provide γ-lactams in acceptable to good yields in dichloromethane, especially when the corresponding titanium enolates are formed. Copyright

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