1599446-26-0

Basic information

• Product Name: C₁₂H₁₀N^(1-)*C₁₂H₈N₂*K⁽¹⁺⁾
• Synonyms: C₁₂H₁₀N^(1-)*C₁₂H₈N₂*K⁽¹⁺⁾
• CAS NO: 1599446-26-0
• Molecular Weight: 387.525
• Mol File: 1599446-26-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₂H₁₀N^(1-)*C₁₂H₈N₂*K⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₁₀N^(1-)*C₁₂H₈N₂*K⁽¹⁺⁾(1599446-26-0)
• EPA Substance Registry System: C₁₂H₁₀N^(1-)*C₁₂H₈N₂*K⁽¹⁺⁾(1599446-26-0)

Safety Data

• Hazardous Substances Data: 1599446-26-0(Hazardous Substances Data)

Upstream product

• 66-71-7 1,10-Phenanthroline 
• 122-39-4 diphenylamine 

Downstream Products

• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 
• 7383-90-6 3,4'-dimethylbiphenyl 
• 611-61-0 2,4'-dimethylbiphenyl 
• 4316-53-4 diphenyl(p-tolyl)amine 

Relevant articles and documents

Reactivity of [K3(phen)8][Cu(NPh2) 2]3 - A possible intermediate in the copper(i)-catalyzed N-arylation of N-phenylaniline

Complex [K3(phen)8][Cu(NPh2) 2]3 (1, phen = phenanthroline) was isolated from the catalytic C-N cross coupling reaction based on the CuI-phen-tBuOK catalytic system. Complex 1 can react with 4-iodotoluene to give 4-methyl-N,N- diphenylaniline (3a) in 50% yield (based on all available NPh2 - ligands of complex 1). In addition, 1 can also work as an effective catalyst for the C-N coupling reactions under the same reaction conditions, indicating that 1 may be an effective intermediate of the catalytic system. In the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO), a radical scavenger, the stoichiometric reaction between complex 1 and 4-iodotoluene was significantly quenched to give a low yield of 12%. The results suggest that the radical path dominates in the reaction, with (phen)KNPh2 as the possible radical source. The structures of 1 and (phen)KNPh2 were both determined by single crystal X-ray diffraction studies.