4316-53-4

Basic information

• Product Name: 4-Methyltriphenylamine
• Synonyms: 4—METHYLTRIPHENYLAMINE;4-Tolyldiphenylamine;4-METHYLTRIPHENYLAMINE,98.0+%(GC);N,N-Diphenyl-p-toluidine;N-(4-Methylphenyl)diphenylamine;Diphenyl p-tolylamine;Diphenyl(4-methylphenyl)amine;Diphenyl(p-methylphenyl)amine
• CAS NO: 4316-53-4
• Molecular Formula: C₁₉H₁₇N
• Molecular Weight: 259.34
• EINECS: 1533716-785-6
• Product Categories: electronic;Acid Anhydrides, etc. (Reagents for Conducting Polymer Research);Functional Materials;Reagents for Conducting Polymer Research
• Mol File: 4316-53-4.mol
• Article Data: 85

Chemical Properties

• Melting Point: 67 °C
• Boiling Point: 393.8 °C at 760 mmHg
• Flash Point: 171.8 °C
• Appearance: /
• Density: 1.095 g/cm³
• Vapor Pressure: 2.08E-06mmHg at 25°C
• Refractive Index: 1.636
• Solubility: soluble in Toluene
• PKA: -2.62±0.30(Predicted)
• CAS DataBase Reference: 4-Methyltriphenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Methyltriphenylamine(4316-53-4)
• EPA Substance Registry System: 4-Methyltriphenylamine(4316-53-4)

Safety Data

• Hazardous Substances Data: 4316-53-4(Hazardous Substances Data)

Usage

Uses

4-Methyltriphenylamine (cas# 4316-53-4) is a useful reactant and reagent in organic reactions and synthesis.

InChI:InChI=1/C19H17N/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3

Upstream product

• 108-86-1 bromobenzene 
• 106-49-0 p-toluidine 
• 624-31-7 4-tolyl iodide 
• 95-50-1 1,2-dichloro-benzene 
• 622-58-2 p-Tolylisocyanate 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 17425-91-1 N-(trimethylsilyl)-diphenylamine 
• 106-43-4 para-chlorotoluene 
• 106-38-7 para-bromotoluene 
• 99-99-0 1-methyl-4-nitrobenzene 
• 122-39-4 diphenylamine 
• 66003-78-9 triphenylsulfonium trifluoromethanesulfonate 
• 1177-35-1 2,4,6-Tris(4-methylphenoxy)-1,3,5-triazine 
• 86-74-8 9H-carbazole 

Downstream Products

• 100308-67-6 4,4′-dibromo-4′′-methyltriphenylamine 
• 122112-54-3 4-[(4-formylphenyl)(4-methylphenyl)amino]benzaldehyde 
• 89115-21-9 4-(N-(4-methylphenyl)-N-phenylamino)benzaldehyde 
• 100803-48-3 N,N-bis[4-(2,2-diphenylethenyl)phenyl]-4-methylaniline 
• 908120-28-5 1-[N-(4-methylphenyl)-N-phenylamino]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene 
• 874914-11-1 4-methyl-N,N-bis(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline 
• 19264-73-4 9-(4-methylphenyl)-9H-carbazole 
• 1202362-88-6 3-methyl-9-phenyl-9H-carbazole 
• 404825-34-9 N,N-di(4-iodophenyl)-4-tolylamine 
• 20441-06-9 N,N'-di(4''-methylphenyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine 
• 65181-78-4 4,4'-bis(m-tolylphenylamino)biphenyl 
• 1643872-88-1 1-(2,5-dimethylthiophen-3-yl)-3-(4-(N-phenyl-N-(4-methylphenyl)amino)phenyl)prop-2-en-1-one 

Relevant articles and documents

A copper(ii) complex as an intermediate of copper(i)-catalyzed C-N cross coupling of N-phenylaniline with aryl halide by in situ ESI-MS study

Complexes [Cu(NPh2)2]-, [Cu(NPh 2)I]- and K[Cu(phen)(NPh2) (p-tolyl)] + were observed by in situ electrospray ionization mass spectrometry (ESI-MS) analysis of the copper(i)-cata

DIARYL AMINE COMPOUND AND METHOD FOR PRODUCING THE SAME

The present invention relates to a process for the preparation of diaryl amine compounds. A compound represented by chemical formula 1, a compound represented by chemical formula 2, and a synthetic reagent in a solvent, the synthetic reagent being CsF, KF, 18 - crown -6, K. 2 CO3, [TBAT] The present invention relates to a process for the preparation of diaryl amine compounds comprising a material selected from the group consisting of a (tetrabutylammonium difluorotriphenylsilicate), TBAF (tetrabutylammonium fluoride) and combinations thereof. Chemical Formula 1. Chemical Formula 2. The diaryl amine compound can be synthesized under the absence of a transition metal to be used to synthesize diaryl amine compounds having various substituents.

A Tetraarylpyrrole-Based Phosphine Ligand for the Palladium-Catalyzed Amination of Aryl Chlorides

A tetraarylpyrrole-based phosphine ligand L1 in combination with Pd(dba)2 provided a catalyst for the Buchwald-Hartwig amination reaction. A variety of amines were rapidly coupled with aryl chlorides at a Pd loading of 0.5 mol%. The selective monoarylation of aliphatic primary amines was achieved in the presence of 0.8 equiv. water. Comparison experiments were also conducted, which revealed that the catalytic activity of L1 is superior to representative phosphine ligands in the Pd-catalyzed C?N coupling of various amines. (Figure presented.).

Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions

A series of novel (NHC)PdCl2-PR3 complexes were synthesized and fully characterized by 1H, 13C, 31P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the same reaction conditions. The solvent-free synthesis of valuable N-aryl carbazoles and similar N-heterocyclic systems was described.