16054-27-6

Basic information

• Product Name: Benzene, 1,1'-(methylcyclopropylidene)bis-, (S)-
• CAS NO: 16054-27-6
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Mol File: 16054-27-6.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(methylcyclopropylidene)bis-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(methylcyclopropylidene)bis-, (S)-(16054-27-6)
• EPA Substance Registry System: Benzene, 1,1'-(methylcyclopropylidene)bis-, (S)-(16054-27-6)

Safety Data

• Hazardous Substances Data: 16054-27-6(Hazardous Substances Data)

Upstream product

• 75854-69-2 ((R)-1-methyl-2,2-diphenyl-cyclopropyl)-phenyl ketone 
• 29834-23-9 R-(-)-(CH₃)3SnC₁₆H₁₅ 
• 124-38-9 carbon dioxide 
• 6526-76-7 (S)-(+)-1-bromo-1-methyl-2,2-diphenylcyclopropane 
• 4542-82-9 (R)-(-)-1-bromo-1-methyl-2,2-diphenylcyclopropane 
• 4542-81-8 (-)-(R)-1-Jod-1-methyl-2,2-diphenyl-cyclopropan 
• 4542-83-0 (-)-(R)-1-Chlor-1-methyl-2,2-diphenyl-cyclopropan 
• 899817-16-4 p-Toluolsulfonsaeure-<(+)-R-4,4-diphenyl-butyl-(2)-ester> 
• 16054-29-8 (+)-(R)-1-Methyl-2,2-diphenyl-cyclopropan-carbaldehyd 
• 108-88-3 toluene 
• 145964-46-1 (-)-2,2-diphenylcyclopropylmethanol 
• 910890-90-3 (R)-4,4-diphenyl-2-butanol 
• 13398-56-6 (-)-(R)-1-bromo-2,2-diphenylcyclopropanecarboxylic acid 
• 149030-27-3 <(+)-1-Brom-2,2-diphenyl-cyclopropyl>-carbinol 

Relevant articles and documents

Mechanism of Organocalcium Reagent Formation.

The stereochemistry of the reaction of (S)-(+)-1-bromo- and (S)-(+)-1-chloro-1-methyl-2,2-diphenylcyclopropane and (S)-(+)-1-bromo-1-(methoxymethyl)-2,2-diphenylcyclopropane with calcium-aromatic complexes is reported as is its reaction with a radical clo

Further evidence of SET mechanism during the LAH reduction of optically active 1-bromo 1-methyl 2,2-diphenyl cyclopropane.

The stereochemical outcome of the reduction os 1(-) (R) with TBTH, SMEAH or LAH shows that with the latter a radical intermediate is involved.