160560-18-9Relevant academic research and scientific papers
Total synthesis of (±)-kellermanoldione: stepwise cycloaddition of a functionalized diene and allenoate
Jung, Michael E.,Cordova, Jesus,Murakami, Masayuki
, p. 3882 - 3885 (2009)
Figur Presented The total synthesis of the diterpene kellermanoldione 1 is reported. Stepwise [4 + 2] cycloaddition of the ketal diene 8 and the allenoste 3 afforded the exo adduct 10x as the major product. It was converted into 1 via six steps, among them a key nonconjugative hydrolysis of a γ-methylene silyl enol ether
Catalytic decarboxylative cross-ketonisation of aryl- and alkylcarboxylic acids using iron catalysts
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Page/Page column 3-4, (2012/07/03)
In the presence of catalytic amounts of magnetite nanopowder, mixtures of aromatic and aliphatic carboxylic acids are converted selectively into the corresponding aryl alkyl ketones. As by-products, only carbon dioxide and water are released. This catalytic cross-ketonisation allows the regioselective acylation of aromatic systems and, thus, represents a sustainable alternative to Friedel-Crafts acylations.
NOVEL DIHYDROPYRIMIDIN-2(1H)-ONE COMPOUNDS AS S-NITROSOGLUTATHIONE REDUCTASE INHIBITORS
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Page/Page column 142-143, (2011/04/24)
The present invention is directed to novel dihydropyrimidin-2(1H)-one compounds useful as S-nitrosoglutathione reductase (GSNOR) inhibitors, pharmaceutical compositions comprising such compounds, and methods of making and using the same.
Catalytic Decarboxylative Cross-Ketonisation of Aryl- and Alkylcarboxylic Acids using Magnetite Nanoparticles
Goossen, Lukas J.,Mamone, Patrizia,Oppel, Christoph
supporting information; experimental part, p. 57 - 63 (2011/03/22)
In the presence of catalytic amounts of magnetite nanopowder, mixtures of aromatic and aliphatic carboxylic acids are converted selectively into the corresponding aryl alkyl ketones. As by-products, only carbon dioxide and water are released. This catalytic cross-ketonisation allows the regioselective acylation of aromatic systems and, thus, represents a sustainable alternative to Friedel-Crafts acylations.
Regiospecific synthesis of 3,4-disubstituted furans and 3-substituted furans using 3,4-bis(tri-n-butylstannyl)furan and 3-(tri-n-butylstannyl)furan as building blocks
Yang,Wong
, p. 9583 - 9608 (2007/10/02)
3,4-Bis(tri-n-butylstannyl)furan and 3-(tri-n-butylstannyl)furan have been prepared and used successfully as building blocks to lead to various 3,4-disubstituted furans and 3-substituted furans, respectively.
The Reaction of Alkyllithium Reagents with Furan-3-carboxylic Acid. A Synthesis of 4-(Furan-3'-yl)-1-methylbutyltriphenylphosphonium Iodide
Dimitriadis, Eugene,Massy-Westropp, Ralph A.
, p. 619 - 627 (2007/10/02)
The ketones, 4-benzyloxy-1-(furan-3'-yl)pentan-1-one and 4-benzyloxy-1-(furan-3'-yl(butan-1-one, have been prepared by generating the required alkyllithium reagent in the presence of lithium furan-3-carboxylate.The latter ketone has been transformed to 4-(furan-3'-yl)-1-methylbutyltriphenylphosphonium iodide.
