16078-91-4

Upstream product

• 103-69-5 N-ethyl-N-phenylamine 
• 106-95-6 allyl bromide 
• 60256-40-8 N-ethyl-N-(2-bromo-allyl)-aniline 
• 107-18-6 allyl alcohol 
• 557-20-0 diethylzinc 
• 98-95-3 nitrobenzene 
• 62-53-3 aniline 
• 556-56-9 allyl iodid 
• 5666-17-1 N,N-diethylallylamine 
• 118-92-3 anthranilic acid 

Downstream Products

• 21184-21-4 ethyl-phenyl-carbamonitrile 
• 15973-79-2 cis-N--N-ethyl-anilin 
• 100-62-9 N-methylenebenzenamine 
• 103-69-5 N-ethyl-N-phenylamine 
• 62-53-3 aniline 
• 91-78-1 1,3,5-triphenylhexahydro-1,3,5-triazine 
• 218598-90-4 N-allyl-N-ethyl-4-(4'-nitrophenyl)azobenzeneamine 
• 218598-86-8 4-formyl-4'-(N-allyl-N-ethylamino)azobenzene 
• 6052-11-5 N-ethylideneaniline 
• 18158-72-0 N-ethyl-N-phenyl-N-propargylamine 

Relevant academic research and scientific papers

Photo-crosslinkable second order nonlinear AB2-type monomers: Convenient synthesis and enhanced NLO thermostability

In this article, two AB2-type second-order nonlinear optical monomers (DN-SH and DS-SH) containing two double bonds and one thiol group, respectively, were synthesized successfully. These two monomers could be in situ photo-crosslinked via a th

Catalyst-Free [2,3]-Sigmatropic Rearrangement Reactions of Photochemically Generated Ammonium Ylides

The rearrangement reaction of ammonium ylides furnishes valuable α,α-disubstituted amino esters. In this work, we describe the visible-light photolysis reaction of aryldiazoacetates in the presence of tertiary amines that react via a free ammonium ylide i

Electrophilic Amination with Nitroarenes

An exceptionally general electrophilic amination, which directly transforms commercially available nitroarenes into alkylated aromatic aminoboranes with zinc organyl compounds was developed. The reaction starts with a two-step partial reduction of the nitro group to a nitrenoid, which is used in situ as the electrophilic amination reagent. To facilitate isolation, the resulting air- and moisture-sensitive aminoboranes were reacted with a range of electrophiles. The method not only represents a direct transformation of nitro compounds into electrophilic amination reagents but also provides an elegant alternative to dehydrocoupling methods for the generation of aminoboranes.

Copper-Catalyzed Dicarbofunctionalization of Unactivated Olefins by Tandem Cyclization/Cross-Coupling

We present a strategy that difunctionalizes unactivated olefins in 1,2-positions with two carbon-based entities. This method utilizes alkyl/arylzinc reagents derived from olefin-tethered alkyl/aryl halides that undergo radical cyclization to generate C(sp3)-Cu complexes in situ, which are intercepted with aryl and heteroaryl iodides. A variety of (arylmethyl)carbo- and heterocycles (N, O) can be synthesized with this new method.

One-Pot Synthesis of O-Allylhydroxylamines through the Organocatalytic Oxidation of Tertiary Allylic Amines Followed by a [2,3]-Meisenheimer Rearrangement

A cheap, green, and highly efficient one-pot method for the synthesis of O-protected allylic alcohols is described. By utilizing 2,2,2-trifluoroacetophenone as the organocatalyst and H2O2 as the oxidant, a variety of allylic amine N-

Sequential Oxidative α-Cyanation/Anti-Markovnikov Hydroalkoxylation of Allylamines

Iron-catalyzed oxidative α-cyanations at tertiary allylamines in the allylic position are followed by anti-Markovnikov additions of alcohols across the vinylic CC double bonds of the initially generated α-amino nitriles. These consecutive reactions generate 2-amino-4-alkoxybutanenitriles from three reactants (allylamines, trimethylsilyl cyanide, and alcohols) in one reaction vessel at ambient temperature.

Direct palladium-catalyzed selective monoallylation of anilines using allylic alcohols

N-Allylation of anilines using allylic alcohols directly to give monoallylic anilines selectively in high yields has been realized by employing palladium acetate-triphenylphosphine as the catalyst. Palladium-catalyzed one-pot cyclization of 2-aminophenols with 2-butene-1,4-diol leads to 3,4-dihydro-2-vinyl-2H-1,4-benzoxazines. (C) 2000 Elsevier Science Ltd.

An efficient palladium-catalyzed route to N-allylanilines by the direct use of allyl alcohols

The direct activation of C-O bonds in allyl alcohols by palladium complexes has been accelerated by carrying out the reactions in the presence of titanium(IV) isopropoxide and molecular sieves (4A). N-Allylation of anilines to give mono- and diallylanilines directly using allyl alcohols has been realized by employing palladium catalysts.