1608-91-9Relevant academic research and scientific papers
The thermal and mass spectral fragmentation of N-butyl thiolo-, thiono-, and dithio-chloroformate
Hudson, Harry R.,Koplick, Andrew J.
, p. 1635 - 1649 (2011)
Thermal decomposition of n-butyl thiolochloroformate at 150C follows a similar pattern to that reported previously for n-butyl chloroformate, to give butyl chloride which is largely rearranged to the s-butyl isomer. An ion-pair mechanism, involving 1,2-and 1,3-hydride shifts, is proposed. The less stable thiono-and dithio-chloroformates decompose to give lower yields of butyl chlorides (mainly without rearrangement) together with numerous other byproducts, indicating the operation of a more complex combination of reaction pathways. The mass spectra of all three thio compounds exhibit molecular ions; the most prominent fragment ions in their spectra are the n-butyl cation, and the radical cations COS+ and CS2+. Numerous chlorine-containing ions of low intensity are also observed, and their mode of formation is discussed. Copyright Taylor &Francis Group, LLC.
GENERATION OF 1,2-ETHANEBIS(TRITHIOCARBONIC ACID) DIANION FROM 2,2'-BIS-1,3-DITHIOLANE AND ITS REACTION WITH ALKYL HALIDES
Tanimoto, Shigeo,Oida, Tatuo,Hatanaka, Kouhei,Sugimoto, Toyonari
, p. 655 - 658 (2007/10/02)
Generation of 1,2-ethanbis(trithiocarbonic acid) dianion from 2,2'-bis-1,3-dithiolane and its reaction with alkyl halides were investigated.
