160874-85-1

Basic information

• Product Name: 2-(4-fluorophenyl)-[1,3,2]-dioxaborolane
• Synonyms: 2-(4-fluorophenyl)-[1,3,2]-dioxaborolane
• CAS NO: 160874-85-1
• Molecular Weight: 165.96
• Mol File: 160874-85-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-(4-fluorophenyl)-[1,3,2]-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-fluorophenyl)-[1,3,2]-dioxaborolane(160874-85-1)
• EPA Substance Registry System: 2-(4-fluorophenyl)-[1,3,2]-dioxaborolane(160874-85-1)

Safety Data

• Hazardous Substances Data: 160874-85-1(Hazardous Substances Data)

Upstream product

• 107-21-1 ethylene glycol 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 1765-93-1 4-fluoroboronic acid 

Downstream Products

• 1250907-52-8 C₁₁H₁₁FO₂ 
• 1250907-71-1 methyl (E)-4-(4-fluorophenyl)-3-butenoate 
• 1229597-21-0 (E)-tert-butyl((4-(4-fluorophenyl)-1-phenylbut-3-en-1-yl)oxy)dimethylsilane 
• 68049-21-8 5-(4-fluorophenyl)pyrimidine 
• 171819-99-1 3,5-bis(4-fluorophenyl)pyridine 
• 374554-36-6 5-(4-fluorophenyl)isoquinoline 
• 144104-44-9 5-(4-fluoro-phenyl)-1H-indole 
• 58861-53-3 4-fluorophenylpyridine 
• 1236889-31-8 (E)-1-fluoro-4-[1-methyl-3-phenyl-2-propen-1-yl]benzene 

Relevant articles and documents

Insight into Copper Catalysis: In Situ Formed Nano Cu2O in Suzuki-Miyaura Cross-Coupling of Aryl/Indolyl Boronates

A ligand-free copper catalyzed Suzuki-Miyaura coupling of 3,5-diiodopyridine with aryl and indole boronates has been explored in good to excellent yields. In situ generation of nano-Cu2O from CuCl2 under the reaction conditions has been discovered for the first time. The generality of the reaction was further demonstrated by the arylation of 5-iodopyrimidine, iodopyridines, iodobenzenes, and diiodobenzenes and resulted in good to moderate yields. Moreover, bisindole alkaloid Scalaridine A has been successfully synthesized in 60% overall yield.

Aerobic alcohol oxidation coupled to palladium-catalyzed alkene hydroarylation with boronic esters

(Chemical Equation Presented) An oxidation exercise: An aerobic alcohol oxidation coupled with a regioselective palladium-catalyzed reductive functionalization of styrenes and arylboronic esters has been developed (see scheme). The mechanism is thought to proceed by initial oxidation of the solvent to generate a PdII-hydride species, which subsequently reacts with the alkene and arylboronic ester to ultimately generate a new C-C bond.

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