73411-22-0

Basic information

• Product Name: 1-phenyl-3,4-dimethyl-3-arsolene
• Synonyms: 1-phenyl-3,4-dimethyl-3-arsolene
• CAS NO: 73411-22-0
• Molecular Weight: 234.173
• Mol File: 73411-22-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-phenyl-3,4-dimethyl-3-arsolene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-3,4-dimethyl-3-arsolene(73411-22-0)
• EPA Substance Registry System: 1-phenyl-3,4-dimethyl-3-arsolene(73411-22-0)

Safety Data

• Hazardous Substances Data: 73411-22-0(Hazardous Substances Data)

Upstream product

• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 73411-24-2 1-phenyl-3-arsolene 
• 696-28-6 dichlorophenylarsine 
• 20738-31-2 hexaphenylcyclohexaarsane 

Downstream Products

• 160954-48-3 1-phenyl-3,4-dimethyl-3-arsolene-1,2-bis(diphenylphosphino)ethane-tricarbonylmolybdenum 
• 696-28-6 dichlorophenylarsine 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 100758-26-7 cis-1,4-dibromo-2,3-dimethyl-2-butene 
• 6044-73-1 (E)-1,4-dibromo-2,3-dimethylbut-2-ene 
• 696-24-2 Phenyldibromoarsine 
• 160954-45-0 1-phenyl-3,4-dimethyl-3-arsolene pentacarbonylchromium 

Relevant articles and documents

Reaktive Arsen-Heterocyclen. III. 3-Arsolene: Synthese und Reaktionen am Arsen

3-Arsolenes (R=Ph, Me, t-Bu, Cl, R'=H, Me) are readily obtained from zirconocene-butadiene complexes and RAsCl2.Alkylation with methyl iodide gives arsonium salts (R=Ph, Me, t-Bu, R'=H, Me), treatment with sulphur gives sulphides (R=Me, t-Bu), while oxidation with Br2 or SO2Cl2 results in ring cleavage.From chloroarsolene substitution products (R=I, H, SPh, OMe, NMe2) as well as coupling products with As-As, As-O-As, and As-S-As units were synthesized.In addition, a number of arsolene complexes with the metals chromium, molybdenum, tungsten, and ruthenium is described. Key words: Arsolene; Zirconocene; Group 6; Ruthenium; Phosphorus

3-Arsolene

3-Arsolenes, R1cyclo(AsCH2C(Me)=C(R2)CH2) (R1 = Ph, Me, t-Bu, R2 = H, Me), are obtained in good yield from chloroarsines, R1AsCl2, and zirconocene diene complexes.They react with methyl iodide at room