1610044-64-8Relevant academic research and scientific papers
Three-component vicinal-diarylation of alkenes: Via direct transmetalation of arylboronic acids
Zhang, Yun,Chen, Gong,Zhao, Dongbing
, p. 7952 - 7957 (2019)
Herein, we report three-component vicinal-diarylation of non-conjugated alkenes initiated by transmetalation of arylboronic acids, which provides complementary access to β,γ-diaryl carbonyl compounds. We have also screened a large number of chiral ligands for developing an enantioselective version of this reaction and obtained the preliminary results (up to 79: 21 e.r.). Notably, the methodology developed herein represents the first three component syn-vicinal-dicarbofunctionalization of non-conjugated alkenes involving palladium catalysis.
Total synthesis of resveratrol-based natural products using a palladium-catalyzed decarboxylative arylation and an oxidative heck reaction
Klotter, Felix,Studer, Armido
, p. 2473 - 2476 (2014/03/21)
Controlled access to resveratrol-based natural products is offered by a novel, modular concept. A common building block readily available on a large scale serves as the starting material for the introduction of structurally important aryl groups by a Pd-c
