161150-55-6

Basic information

• Product Name: BENZYL (2R,3R)-1,3-DIHYDROXYBUTAN-2-YLCARBAMATE
• Synonyms: BENZYL (2R,3R)-1,3-DIHYDROXYBUTAN-2-YLCARBAMATE
• CAS NO: 161150-55-6
• Molecular Formula: C₁₂H₁₇NO₄
• Molecular Weight: 239.269
• Mol File: 161150-55-6.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: BENZYL (2R,3R)-1,3-DIHYDROXYBUTAN-2-YLCARBAMATE(CAS DataBase Reference)
• NIST Chemistry Reference: BENZYL (2R,3R)-1,3-DIHYDROXYBUTAN-2-YLCARBAMATE(161150-55-6)
• EPA Substance Registry System: BENZYL (2R,3R)-1,3-DIHYDROXYBUTAN-2-YLCARBAMATE(161150-55-6)

Safety Data

• Hazardous Substances Data: 161150-55-6(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 114102-50-0 C₁₇H₂₃NO₇ 
• 57224-63-2 methyl (2S,3R)-2-(benzyloxycarbonylamino)-3-hydroxybutyrate 
• 19728-63-3 N-benzyloxycarbonyl-L-treonine 

Downstream Products

• 1224962-19-9 (2R,3R)-2-(benzyloxycarbonylamino)-3-hydroxybutyl 4-methylbenzenesulfonate 
• 1379661-59-2 C₁₇H₂₆N₂O₃ 
• 1379661-60-5 benzyl (2R,3R)-3-(tert-butyldimethylsilyloxy)-1-(piperidin-1-yl)butan-2-ylcarbamate 
• 560130-31-6 (2R)-3-(benzyloxycarbonyl)amino-3,3-dimethoxybutanol 
• 560130-33-8 (Z)-3-(benzyloxycarbonyl)amino-4-hydroxybut-3-en-2-one 
• 560130-27-0 (2R)-3-(benzyloxycarbonyl)amino-3,3-dimethoxybutanal 
• 873000-97-6 Benzoic acid (R)-2-benzyloxycarbonylamino-3-oxo-butyl ester 
• 161150-58-9 [1-(tert-butyldiphenylsilanyloxymethyl)-2,2-dimethoxypropyl]carbamic acid benzyl ester 
• 161150-57-8 [1-(tert-butyldiphenylsilanyloxymethyl)-2-oxopropyl]carbamic acid benzyl ester 
• 873000-98-7 Benzoic acid (2R,3R)-2-benzyloxycarbonylamino-3-hydroxy-butyl ester 
• 3228-51-1 L-threoninol 
• 161150-56-7 [1-(tert-butyldiphenylsilanyloxymethyl)-2-hydroxypropyl]carbamic acid benzyl ester 

Relevant articles and documents

Highly stable triple helix formation by homopyrimidine (l)-acyclic threoninol nucleic acids with single stranded DNA and RNA

Acyclic (l)-threoninol nucleic acid (aTNA) containing thymine, cytosine and adenine nucleobases were synthesized and shown to form surprisingly stable triplexes with complementary single stranded homopurine DNA or RNA targets. The triplex structures consist of two (l)-aTNA strands and one DNA or RNA, and these triplexes are significantly stronger than the corresponding DNA or RNA duplexes as shown in competition experiments. As a unique property the (l)-aTNAs exclusively form triplex structures with DNA and RNA and no duplex structures are observed by gel electrophoresis. The results were compared to the known enantiomer (d)-aTNA, which forms much weaker triplexes depending upon temperature and time. It was demonstrated that (l)-aTNA triplexes are able to stop primer extension on a DNA template, showing the potential of (l)-aTNA for antisense applications. This journal is

New chiral iminium salt catalysts for asymmetric epoxidation

A range of enantiomerically pure 4-substituted 5-amino-1,3-dioxanes has been condensed with 2-(2-bromoethyl)benzaldehyde to produce chiral dihydroisoquinolinium salts, which are effective asymmetric catalysts for the epoxidation of simple alkenes, giving ees of up to 71 %. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

Synthetic studies of carzinophilin. Part 2: Synthesis of 3,4-dibenzyloxy-2-methylidene-1-azabicyclo[3.1.0]hexane systems corresponding to the C1-C17 fragment of carzinophilin

A model compound bearing the C1-C17 fragment of carzinophilin was synthesized. The synthesis involved coupling reaction of a cyclic thioimidate with the 4H-oxazol-5-one derivative, ring-opening of the 4H-oxazol-5-one to furnish a dehydropeptide system, elaboration of the C1-C6 enolamide, and construction of the aziridine ring as key steps.