161288-99-9

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 3765-95-5 methyl β-fructopyranoside 
• 161288-97-7 methyl 5-bromo-5-deoxy-1,3-O-isopropylidene-α-L-sorbopyranoside 
• 161288-96-6 methyl 5-bromo-5-deoxy-α-L-sorbopyranoside 
• 930-69-8 sodium thiophenolate 
• 161288-98-8 methyl 5-bromo-5-deoxy-4-O-tert-butyldimethylsilyl-1,3-O-isopropylidene-α-L-sorbopyranoside 

Downstream Products

• 199439-03-7 ((4aR,7R,8S,8aS)-7-Benzenesulfinyl-4a-methoxy-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy)-tert-butyl-dimethyl-silane 

Relevant academic research and scientific papers

Novel Pyranoid Glycals Derived from D-Fructose

A range of 5,6-glycals have been prepared from methyl β-D-fructopyranoside and their chemistry investigated.

The synthesis and reactions of some novel pyranoid 5,6-glycals derived from D-fructose

In this paper, we describe a new synthetic pathway to ketopyranose 5,6-glycals. We also demonstrate the utility of these derivatives for preparing C(6)-functionalised ketopyranosides.