3765-95-5

Basic information

• Product Name: methyl hex-2-ulopyranoside
• CAS NO: 3765-95-5
• Molecular Formula: C₇H₁₄O₆
• Molecular Weight: 194.1825
• Mol File: 3765-95-5.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 380.9°C at 760 mmHg
• Flash Point: 184.2°C
• Density: 1.48g/cm³
• Vapor Pressure: 2.29E-07mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: methyl hex-2-ulopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl hex-2-ulopyranoside(3765-95-5)
• EPA Substance Registry System: methyl hex-2-ulopyranoside(3765-95-5)

Safety Data

• Hazardous Substances Data: 3765-95-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 57-48-7 D-Fructose 
• 6347-01-9 fructopyranose 
• 57-50-1 Sucrose 
• 470-23-5 D-fructose 
• 7660-25-5 D-fructose 
• 7647-01-0 hydrogenchloride 
• 50-99-7 D-glucose 

Downstream Products

• 20880-92-6 2,3;4,5-di-O-isopropylidene-β-D-fructopyranose 
• 4451-14-3 methyl-(tetra-O-methyl-α-L-sorbopyranoside) 
• 53416-07-2 β-D-fructopyranoside, ethyl 
• 1820-84-4 2-ethyl-β-D-fructofuranoside 
• 81024-99-9 ethyl α-D-fructofuranoside 
• 78136-15-9 methyl 1,3,4,5-tetra-O-benzyl-α-L-sorbopyranoside 
• 528584-68-1 methyl (methyl β-D-fructopyranoside)uronate 
• 528584-68-1 methyl (methyl β-L-sorbopyranoside)uronate 
• 78136-16-0 2,3,4,6-tetra-O-benzyl-D-glucitol 
• 78184-86-8 1,3,4,5-tetra-O-benzyl-α-L-sorbopyranoside 
• 78136-16-0 (2S,3R,4R,5S)-2,3,4,6-tetrakis(benzyloxy)hexane-1,5-diol 

Relevant articles and documents

A Systematic Study of Metal Triflates in Catalytic Transformations of Glucose in Water and Methanol: Identifying the Interplay of Br?nsted and Lewis Acidity

The specific type of acidity associated with the given metal trifloromethanesulfonates (Br?nsted or Lewis acidity) dramatically influences the course of reactions, and it is possible to select for disaccharides, fructose, methyl glucosides, or methyl levulinate. Glucose is transformed into a range of value-added molecules in water and methanol under the action of acidic metal triflates as catalysts, including their analogous Br?nsted acid-assisted or Br?nsted base-modified systems. A systematic study is presented of a range of metal triflates in methanol and water, pinning down the preferred conditions to select for each product.

An approach towards the synthesis of sialyl nucleoside mimetics

An approach towards the synthesis of novel sialyl nucleoside mimetics based on d-fructose is described. The synthesis of these mimetics is achieved in good overall yield in seven steps. The key synthetic step is the coupling reaction of pyrimidine bases (uracil, 5-fluorouracil and cytosine) to the C-1 position of the modified D-tagatofructofuranoside.

Reaction of D-fructose, D-glucose and inulin with alcohols in the presence of iodine; a novel glycosidation procedure

An efficient procedure for the glycosidation of D-fructose and D-glucose catalyzed by iodine is described. The reaction yields mainly alkyl glycofuranosides. Treatment of inulin under similar conditions leads to inter-glycosidic bond cleavage and to formation of alkyl D-fructofuranosides. The reaction conditions are particularly mild and relatively selective.