1616494-83-7

Basic information

• Product Name: 2-acetamido-N-benzyl-N-phenylbenzamide
• CAS NO: 1616494-83-7
• Molecular Weight: 344.413
• Mol File: 1616494-83-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-acetamido-N-benzyl-N-phenylbenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-acetamido-N-benzyl-N-phenylbenzamide(1616494-83-7)
• EPA Substance Registry System: 2-acetamido-N-benzyl-N-phenylbenzamide(1616494-83-7)

Safety Data

• Hazardous Substances Data: 1616494-83-7(Hazardous Substances Data)

Upstream product

• 552-16-9 ortho-nitrobenzoic acid 
• 610-14-0 2-nitrobenzyl chloride 
• 2385-27-5 N-phenyl-2-nitrobenzamide 
• 682785-16-6 N-benzyl-2-nitro-N-phenylbenzamide 
• 108898-01-7 2-amino-N-benzyl-N-phenylbenzamide 
• 75-36-5 acetyl chloride 

Downstream Products

• 1616494-92-8 5-acetyl-7-benzyl-5H-dibenzo[d,f][1,3]diazepin-6(7H)-one 

Relevant articles and documents

Intramolecular metal-free oxidative aryl-aryl coupling: An unusual hypervalent-iodine-mediated rearrangement of 2-substituted n-phenylbenzamides

Hypervalent-iodine-mediated oxidative coupling of the two aryl groups in either 2-acylamino-N-phenyl-benzamides or 2-hydroxy-N-phenylbenzamides, with concomitant insertion of the ortho-substituted N or O atom into the tether, has been described for the first time. This unusual metal-free rearrangement reaction involves an oxidative C(sp2)?C(sp2) aryl-aryl bond formation, cleavage of a C(sp2)?C(O) bond, and a lactamization/lactonization. Furthermore, unsymmetrical diaryl compounds can be easily obtained by removing the tether within the cyclized product.