161807-05-2Relevant articles and documents
Synthesis and properties of optically active 6,6′-didodecyl-1,1′-binaphthyl-phthalocyanine linked through crown ether units
Liu, Hongwei,Liu, Yaohu,Liu, Minghua,Chen, Chuanfu,Xi, Fu
, p. 7083 - 7086 (2001)
A novel optically active 6,6′-didodecyl-1,1′-binaphthyl-metallophthalocyanine linked through crown ether units ((S)-Pc) has been synthesized. A stable monolayer of (S)-Pc that is able to bind metal ions can be formed at the air-water interface. Nonlinear
Synthesis and copper(I)-driven disaggregation of a zinc-complexed phthalocyanine bearing four lateral coordinating rings
Martynov, Alexander G.,Gorbunova, Yulia G.,Nefedov, Sergey E.,Tsivadze, Aslan Y.,Sauvage, Jean-Pierre
, p. 6888 - 6894 (2013/02/22)
A new zinc phthalocyaninate, bearing four flexible phenanthroline- containing 30-membered rings was synthesized by template condensation of a macrocyclic phthalonitrile. The resulting phthalocyanine was an insoluble aggregate. However, in the presence of CuI ions, the formation of a soluble complex was observed. UV/Vis and DOSY NMR spectroscopic studies showed a monomolecular state for this species in solution. 1H-1H ROESY demonstrated that the macrocyclic substituents adopt a folded conformation, giving the complex a globular shape. The folding originates from stacking interactions between the phthalocyanine core and peripheral copper(I)-phenanthroline complexes. Copyright
1,2-Dicyano-4,5-bis[2'-(2"-benzyloxyethoxy)ethoxy]benzene-precursor towards new functionalized phthalocyanines
Martynov, Alexander G.,Gorbunova, Yulia G.,Tsivadze, Aslan Yu.,Sauvage, Jean-Pierre
, p. 237 - 238 (2011/03/20)
1,2-Dicyano-4,5-bis[2'-(2"-benzyloxyethoxy)ethoxy]benzene can act as a precursor to new functionalized phthalocyanines with liquid crystal properties.
Synthesis of optically active 1,1′-binaphthyl-phthalocyanines linked via a crown ether unit
Liu, Hong-Wei,Chen, Chuan-Fu,Ai, Min,Gong, Ai-Jun,Jiang, Jing,Xi, Fu
, p. 4915 - 4922 (2007/10/03)
Novel optically active metal and metal-free phthalocyanines, substituted with 1,1′-binaphthyl crown ether units, have been synthesized and characterized.
Synthesis and supramolecular chemistry of novel liquid crystalline crown ether-substituted phthalocyanines: Toward molecular wires and molecular ionoelectronics
Van Nostrum, Cornelus F.,Picken, Stephen J.,Schouten, Arend-Jan,Nolte, Roeland J. M.
, p. 9957 - 9965 (2007/10/03)
The synthesis of the metal-free and the dihydroxysilicon derivatives of tetrakis[4′,5′-bis(decoxy)benzo-18-crown-6]phthalocyanine is described. The metal-free phthalocyanine is liquid crystalline and exhibits a crystalline phase to mesophase transition at