1620093-17-5

Basic information

• Product Name: 1-((4-fluorophenyl)ethynyl)-3,3-bis(trifluoromethyl)-1,3-dihydro-1λ³-benzo[d][1,2]iodaoxole
• Synonyms: 1-((4-fluorophenyl)ethynyl)-3,3-bis(trifluoromethyl)-1,3-dihydro-1λ³-benzo[d][1,2]iodaoxole
• CAS NO: 1620093-17-5
• Molecular Weight: 488.143
• Mol File: 1620093-17-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-((4-fluorophenyl)ethynyl)-3,3-bis(trifluoromethyl)-1,3-dihydro-1λ³-benzo[d][1,2]iodaoxole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-((4-fluorophenyl)ethynyl)-3,3-bis(trifluoromethyl)-1,3-dihydro-1λ³-benzo[d][1,2]iodaoxole(1620093-17-5)
• EPA Substance Registry System: 1-((4-fluorophenyl)ethynyl)-3,3-bis(trifluoromethyl)-1,3-dihydro-1λ³-benzo[d][1,2]iodaoxole(1620093-17-5)

Safety Data

• Hazardous Substances Data: 1620093-17-5(Hazardous Substances Data)

Upstream product

• 130995-12-9 1-(4-fluorophenyl)-2-trimethylsilylacetylene 
• 76215-48-0 1-chloro-3,3-bis(trifluoromethyl)-1,3-dihydro-1λ³-benzo[d][1,2]iodaoxole 
• 76215-47-9 1,1,1,3,3,3-hexafluoro-2-(2-iodophenyl)-propan-2-ol 
• 718-64-9 1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol 

Downstream Products

• 766-98-3 1-ethynyl-4-fluorobenzene 
• 886-66-8 1,4-diphenyl-1,3-butadiyne 
• 76215-47-9 1,1,1,3,3,3-hexafluoro-2-(2-iodophenyl)-propan-2-ol 
• 791-28-6 Triphenylphosphine oxide 

Relevant articles and documents

Dual Gold/Silver Catalysis: Indolizines from 2-Substituted Pyridine Derivatives via a Tandem C(sp3)–H Alkynylation/Iminoauration

A dual gold/silver-catalyzed cascade C(sp3)–H alkynylation/iminoauration of 2-substituted pyridines with hypervalent iodine(III) reagents for the synthesis of indolizines is described. This novel reaction involves the formation of an alkynyl Au(III) species, a dual gold/silver-catalyzed C(sp3)–H functionalization, and a subsequent iminoauration process. A number of indolizines bearing diverse functionalities were prepared in good to excellent yield. Furthermore, a gram-scale reaction was efficiently conducted.