162052-57-5Relevant academic research and scientific papers
Silyl migration in the photochemical reactions of 2- trimethylsilylmethylphenyl ketones
Saito, Masaichi,Saito, Akitomo,Ishikawa, Yuko,Yoshioka, Michikazu
, p. 3139 - 3141 (2005)
(Chemical Equation Presented) Irradiation of 2-trimethylsilylmethylphenyl ketones 1 gives benzocyclobutenols 2 and 5 together with siloxybenzocyclobutenes 4. Compound 4 arises from the novel photoinduced 1,5-silyl migration of 1. Irradiation of 1 in the p
Formation of Benzocyclobuten-1-ol Derivatives by Intramolecular Cylization of o-Acylbenzyllithiums
Kobayashi, Kazuhiro,Kawakita, Masataka,Mannami, Tohru,Konishi, Hisatoshi
, p. 733 - 736 (1995)
Reaction between the carbanions, generated in situ by the treatment of o-(trimethylsilylmethyl)phenyl ketones with lithium diisopropylamide (LDA), and chlorotrimethylsilane affords the corresponding 1-(trimethylsilyloxy)-2-trimethylsilybenzocyclobutene de
Ruthenium-catalyzed carbon-carbon bond formation via the cleavage of an unreactive aryl carbon-nitrogen bond in aniline derivatives with organoboronates
Ueno, Satoshi,Chatani, Naoto,Kakiuchi, Fumitoshi
, p. 6098 - 6099 (2008/02/08)
The RuH2(CO)(PPh3)3-catalyzed reaction of 2-amino-6-methylacetophenone with phenylboronic acid 2,2-dimethyl-1,3-propanediol ester in refluxing toluene gave the corresponding phenylation product in 83% yield via aryl carbon
Intramolecular Cyclizations of o-Acylbenzyllithiums. Formation of Benzocyclobuten-1-ol Derivatives and Their Thermal Isomerization
Kobayashi, Kazuhiro,Kawakita, Masataka,Uchida, Masaharu,Nishimura, Koichi,Mannami, Tohru,Irisawa, Susumu,Morikawa, Osamu,Konishi, Hisatoshi
, p. 3557 - 3562 (2007/10/03)
The formation of benzocyclobutenol derivatives by intramolecular cyclizations of o-acylbenzyllithiums is described. Treatment of o-(trialkylsilylmethyl)phenyl ketones with lithium diisopropylamide (LDA) followed by quenching of the resulting benzylic carb
