1620697-54-2Relevant academic research and scientific papers
Highly enantioselective hydrogenation of steric hindrance enones catalyzed by Ru complexes with chiral diamine and achiral phosphane
Chen, Xiangning,Zhou, Han,Zhang, Kunyu,Li, Jiawen,Huang, Hanmin
, p. 3912 - 3915 (2014/08/18)
An asymmetric hydrogenation of sterically hindered β,β- disubstituted enones has been well-established by using a ruthenium complex composed of an achiral diphosphane and a chiral diamine as catalyst, wherein the carbonyl group was selectively hydrogenated to give a wide range of chiral allylic alcohols with high levels of enantioselectivity and complete chemoselectivity.
