162085-16-7

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 162085-15-6 (E)-4-methyl-7-phenyl-heptan-4-ene-1-ol 
• 70388-36-2 (E)-4-methyl-7-phenyl hept-4-ene-oate 
• 123718-22-9 (+/-)-2-methyl-5-phenylpent-1-en-3-ol 
• 104-53-0 3-phenyl-propionaldehyde 
• 187336-21-6 (E)-6-(tert-butyldiphenylsilyloxy)-3-methylhex-2-enyl acetate 
• 187336-22-7 (E)-6-(tert-butyldiphenylsilyloxy)-3-methylhex-2-en-1-ol 
• 100045-79-2 <(2E)-6-Hydroxy-3-methyl-2-hexenyl>acetat 
• 35334-60-2 (E)-6-acetoxy-4-methyl-4-hexenal 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 37715-31-4 (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enyl acetate 
• 917611-89-3 (E)-6-(tert-butyldiphenylsilyloxy)-3-methylhex-2-enyl diethyl phosphate 

Downstream Products

• 169217-02-1 (E)-(7-iodo-4-methylhept-3-enyl)benzene 
• 162085-08-7 (E)-6-methyl-9-phenyl-1,1,1-trifluoronona-5-ene-2-one 
• 917612-30-7 (E)-6-methyl-9-phenylnon-6-en-2-one 
• 917612-13-6 (E)-5-methyl-8-phenyloct-5-enenitrile 

Relevant academic research and scientific papers

Catalytic diastereoselective polycyclization of homo(polyprenyl)arene analogues bearing terminal siloxyvinyl groups

Highly diastereoselective polycyclization of homo(polyprenyl)arene analogues bearing terminal siloxyvinyl groups was catalyzed by tin(IV) chloride (10 mol %). The cyclizations of tert-butyldiphenylsilyl and triisopropylsilyl polyenol ethers gave 4α(equatorial)- and 4β(axial)-siloxypolycycles as major isomers, respectively. The strong nucleophilicity of pro-C(9), a (6E) geometry, and a bulky silyl group effectively favored the 4α-preference, whereas the weak nucleophilicity of pro-C(9), a (6Z)-geometry, and less steric hindrance of a silyl group favored the 4β-preference.

Tandem carbonyl ene cyclization-cycloalkylation: A route to trifluoromethyl diterpenoids

A new sequential carbonyl-ene cyclization/cycloalkylation of trifluoromethyl ketones catalyzed by aluminum Lewis acids is described. From ketone 1, the 4-CF3-4-OH cis-octahydrophenanthrene 6 is obtained in 50% yield. From ketone 2, with MeAlCl