16215-47-7Relevant articles and documents
Copper(ii)-catalyzed protoboration of allenes in aqueous media and open air
Nekvinda, Jan,Santos, Webster L.,Snead, Russell F.
supporting information, p. 14925 - 14931 (2021/09/04)
A method has been developed for the facile Cu(ii)-catalyzed protoboration of monosubstituted allenes in aqueous media under atmospheric conditions. The reaction occurs site selectively, favoring internal alkene protoboration to afford 1,1-disubstituted vinylboronic acid derivatives (up to 93?:?7) with modest to good yields. The method has been applied to a variety of phenylallene derivatives as well as alkyl-substituted allenes. This journal is
Expanding the regioselective enzymatic repertoire: Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta
Paul, Caroline E.,Rajagopalan, Aashrita,Lavandera, Ivan,Gotor-Fernandez, Vicente,Kroutil, Wolfgang,Gotor, Vicente
supporting information; experimental part, p. 3303 - 3305 (2012/04/23)
The first report of a biocatalytic regioselective oxidative mono-cleavage of dialkenes was successfully achieved employing a cell-free enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivities. The Royal Society of Chemistry 2012.
Method for production of allyloxystyrene compounds
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, (2008/06/13)
Allylic styrene ether compounds of the formula: STR1 where R1 is an optionally substituted allylic or propargyl hydrocarbon group, and R2, R3, and R4 are independently H, C1-6 hydrocarbon or C1-6