162329-04-6

Basic information

• Product Name: (E,1'S,3R,R_S)-3-(1'-methyl-3'-phenylsulphinyl-2'-propenyl)cyclohexan-1-one
• Synonyms: (E,1'S,3R,R_S)-3-(1'-methyl-3'-phenylsulphinyl-2'-propenyl)cyclohexan-1-one
• CAS NO: 162329-04-6
• Molecular Weight: 276.4
• Mol File: 162329-04-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E,1'S,3R,R_S)-3-(1'-methyl-3'-phenylsulphinyl-2'-propenyl)cyclohexan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E,1'S,3R,R_S)-3-(1'-methyl-3'-phenylsulphinyl-2'-propenyl)cyclohexan-1-one(162329-04-6)
• EPA Substance Registry System: (E,1'S,3R,R_S)-3-(1'-methyl-3'-phenylsulphinyl-2'-propenyl)cyclohexan-1-one(162329-04-6)

Safety Data

• Hazardous Substances Data: 162329-04-6(Hazardous Substances Data)

Upstream product

• 162329-01-3 (2S,R_S)-1-(phenylsulfinyl)butan-2-ol 
• 67210-33-7 (S)-(+)-1-(benzenesulfanyl)-2-butanol 
• 57814-09-2 1-(phenylthio)-2-butanone 
• 67210-33-7 (±)-1-(phenylthio)butan-2-ol 
• 100-68-5 methyl-phenyl-thioether 
• 930-68-7 cyclohexenone 
• 162427-87-4 [(R)-((E)-But-1-ene)-1-sulfinyl]-benzene 

Downstream Products

• 162329-08-0 methyl (E,1'S,4R)-4-(1'-methyl-3'-phenylthio-2'-propenyl)cyclohex-1-ene-1-carboxylate 
• 58493-52-0 methyl (4R,1'R,3'RS)-(+)-4-(1',5'-dimethyl-3'-hydroxyhexyl)-1-cyclohexenecarboxylate 
• 145353-92-0 methyl (1'R,4R)-4-(2'-formyl-1'-methylethyl)cyclohex-1-ene-1-carboxylate 
• 17904-27-7 (+)-(4R)-[(S)-1,5-dimethyl-3-oxohexyl]cyclohex-1-enecarboxylic acid methyl ester 
• 162329-05-7 (E,1'S,3R)-3-(1'-methyl-3'-phenylthio-2'-propenyl)cyclohexan-1-one 

Relevant articles and documents

Synthesis of compounds with juvenile hormone activity; XXXI: Stereocontrolled synthesis of (+)-juvabione from a chiral sulfoxide

A stereocontrolled synthesis of (+)-juvabione is described. The key step is a regioselective lithiation of a chiral (E)-butenyl sulfoxide 5 followed by stereoselective 1,4-addition to cyclohex-2-en-1-one. The chiral sulfoxide 5 was prepared by employing a