162427-87-4

Upstream product

• 162329-01-3 (2S,R_S)-1-(phenylsulfinyl)butan-2-ol 
• 67210-33-7 (S)-(+)-1-(benzenesulfanyl)-2-butanol 
• 57814-09-2 1-(phenylthio)-2-butanone 
• 67210-33-7 (±)-1-(phenylthio)butan-2-ol 
• 100-68-5 methyl-phenyl-thioether 

Downstream Products

• 162329-04-6 (E,1'S,3R,R_S)-3-(1'-methyl-3'-phenylsulphinyl-2'-propenyl)cyclohexan-1-one 
• 162329-08-0 methyl (E,1'S,4R)-4-(1'-methyl-3'-phenylthio-2'-propenyl)cyclohex-1-ene-1-carboxylate 
• 162329-05-7 (E,1'S,3R)-3-(1'-methyl-3'-phenylthio-2'-propenyl)cyclohexan-1-one 

Relevant academic research and scientific papers

Synthesis of compounds with juvenile hormone activity; XXXI: Stereocontrolled synthesis of (+)-juvabione from a chiral sulfoxide

A stereocontrolled synthesis of (+)-juvabione is described. The key step is a regioselective lithiation of a chiral (E)-butenyl sulfoxide 5 followed by stereoselective 1,4-addition to cyclohex-2-en-1-one. The chiral sulfoxide 5 was prepared by employing a