162378-88-3

Basic information

• Product Name: tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)
• Synonyms: tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)
• CAS NO: 162378-88-3
• Molecular Weight: 952.615
• Mol File: 162378-88-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)(CAS DataBase Reference)
• NIST Chemistry Reference: tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)(162378-88-3)
• EPA Substance Registry System: tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)(162378-88-3)

Safety Data

• Hazardous Substances Data: 162378-88-3(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 16654-89-0 sodium 2,6-di-tert-butyl-4-methylphenoxide 
• 10361-82-7 samarium(III) chloride 
• 7440-19-9 samarium 
• 936842-48-7 (2,6-di-tert-butyl-4-methylphenolato)trimethyltin(IV) 

Relevant articles and documents

Synthesis and crystal structure of a four-coordinate aryloxo samarium complex [Sm(OAr)3(THF)](THF) (OAr=2.6-ditertbutyl-4-methylphenoxo)

The aryloxo samarium complex [Sm(ArO)3(THF)](THF) has been prepared by the reaction of SmCl3 with 3 equiv. of NaOAr in THF. An X-ray crystallographic analysis shows the complex to be a four-coordinate aryloxide complex. Three oxygen atoms of aryloxo and one oxygen atom of THF coordinate to the samarium to form a distorted tetrahedron. The average Sm-O(Ar) distance is 2.151(7) ?.