175444-04-9Relevant academic research and scientific papers
Push-pull quinoidal porphyrins
Smith, Martin J.,Blake, Iain M.,Clegg, William,Anderson, Harry L.
supporting information, p. 3648 - 3654 (2018/05/26)
A family of push-pull quinoidal porphyrin monomers has been prepared from a meso-formyl porphyrin by bromination, thioacetal formation, palladium-catalyzed coupling with malononitrile and oxidation with DDQ. Attempts at extending this synthesis to a push-
The Heck reaction for porphyrin functionalisation: Synthesis of meso-alkenyl monoporphyrins and palladium-catalysed formation of unprecedented meso-β ethene-linked diporphyrins
Locos, Oliver B.,Arnold, Dennis P.
, p. 902 - 916 (2007/10/03)
Palladium-catalysed coupling of the vinyl derivatives methyl acrylate, styrene and acrylonitrile with 5-bromo-10,15,20-triphenylporphyrin (MTriPPBr; M = 2H, Ni, Zn) and 5,15-dibromo-10,20-bis(3,5-di-tert-butylphenyl)porphyrin (MDAPBr2) produced
