163231-36-5

Upstream product

• 7089-68-1 2-chloro-[1,10]phenanthroline 
• 104849-76-5 Benzylidene-tributyl-λ⁵-phosphane 
• 578-66-5 8-amino quinoline 
• 66-71-7 1,10-Phenanthroline 
• 766-04-1 benzyllithium 
• 1100-88-5 benzyltriphenylphosphonium chloride 

Downstream Products

• 876127-12-7 [(2-benzoyl-1,10-phenanthroline 2,6-diethylanil)]FeCl₂ 
• 876126-92-0 2-benzoyl-1,10-phenanthroline(2,6-diethylanil) 
• 163231-33-2 2-[1-(2,4-Dinitro-phenyl)-meth-(Z)-ylidene]-1,2-dihydro-[1,10]phenanthroline 
• 163231-34-3 2-(2',4'-dinitrobenzyl)-1,10-phenanthroline 

Relevant academic research and scientific papers

N ortho acyl substituted nitrogen-containing heterocyclic compound and process for preparing aminal iron (II) complexes thereof

Provided are a process for preparing an N ortho acyl substituted nitrogen-containing heterocyclic compound and an aminal iron (II) complex thereof, and the use of the complexes obtained by the process in an olefin oligomerization catalyst. The N ortho acyl substituted nitrogen-containing heterocyclic compound in the present invention is for example 2-acyl-1,10-phenanthroline or 2,6-diacetyl pyridine as shown in formula b, and the N ortho acyl substituted nitrogen-containing heterocyclic compound in the present invention is produced by a reaction of a precursor thereof in a substituted or unsubstituted nitrobenzene. Preferably the precursor shown in formula I in the present invention is produced by 1,10-phenanthroline reacting with trialkyl aluminum, or a halogenoalkyl aluminum RnAIXm, or a substituted or unsubstituted benzyl lithium Ph′CH2Li, followed by hydrolysis. The preparation method provided in the present invention has a few synthetic steps, an easy process, a low toxic effect, and reduces the preparation costs of the catalyst, and has a promising outlook in the industrial application.

A new practical approach towards the synthesis of unsymmetric and symmetric 1,10-phenanthroline derivatives at room temperature

An efficient method towards synthesis of 1,10-phenanthrolines is described. Through Lewis acid-catalyzed annulation reaction between 3-ethoxycyclobutanones and 8-aminoquinolines, a variety of unsymmetric and symmetric 1,10-phenanthroline derivatives were

Proton-Transfer Processes in Well-Defined Media: Experimental Investigation of Photoinduced and Thermal Proton-Transfer Processes in Single Crystals of 2-(2,4-Dinitrobenzyl)pyridine Derivatives

A detailed spectroscopic study of photoinduced and thermally activated proton-transfer processes for a series of different crystals of 2-(2,4-dinitrobenzyl)pyridine derivatives has been performed.The quantitative analysis of ground- and excited-state activation barriers and preexponential factors in deuterated and nondeuterated crystals shows clearly that the observed photochromism is linked to a proton-transfer process.Furthermore, it is clearly seen that the supramolecular environment of the transferred proton participates in the proton-transfer process.These supramolecular effects control the relative rates and efficiencies of the observed proton-transfer processes in both the ground and excited state, yielding, at room temperature, photoproducts having lifetimes ranging between hours and weeks.At least two proton-accepting groups may be active in the abstraction of the proton from its relatively stable benzylic position.Additionally, low-temperature measurements of proton-transfer processes show that tunneling processes prevail at temperatures below 100 K only in the excited state.No evidence for tunneling could be found for ground-state processes.

Long-lived Photoinduced Proton Transfer Processes

Irradiation of the phenanthroline-dinitrobenzyl compound 3 generates, via a photoinduced proton transfer process, a long-lived tautomer having a lifetime about 5*103 times longer than that of the parent compound 1a.