7089-68-1

Basic information

• Product Name: 2-Chloro-1,10-phenanthroline
• Synonyms: chlorophenanthroline;2-CHLORO-1,10-PHENANTHROLINE;2-Chloro-1,10-diazaphenanthrene;VUF 7730;2-Chloro-1,10-phenan;1,10-Phenanthroline, 2-chloro-;2-Chloro-1,10-phenthroline
• CAS NO: 7089-68-1
• Molecular Formula: C₁₂H₇ClN₂
• Molecular Weight: 214.65
• Mol File: 7089-68-1.mol
• Article Data: 18

Chemical Properties

• Melting Point: 130 °C
• Boiling Point: 391.8°C at 760 mmHg
• Flash Point: 222.9°C
• Appearance: /
• Density: 1.375
• Vapor Pressure: 5.43E-06mmHg at 25°C
• Refractive Index: 1.741
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility: soluble in Methanol
• PKA: 4.22±0.10(Predicted)
• CAS DataBase Reference: 2-Chloro-1,10-phenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Chloro-1,10-phenanthroline(7089-68-1)
• EPA Substance Registry System: 2-Chloro-1,10-phenanthroline(7089-68-1)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 7089-68-1(Hazardous Substances Data)

Usage

Chemical Properties

Light yellow solid

InChI:InChI=1/C12H7ClN2/c13-10-6-5-9-4-3-8-2-1-7-14-11(8)12(9)15-10/h1-7H

Upstream product

• 5144-89-8 1,10-phenanthroline hydrate 
• 22426-17-1 2-phenoxy-1,10-phenanthroline 
• 92695-50-6 1H-[1,10]phenanthrolin-2-one 
• 23647-26-9 1-methyl-1,10-phenanthrolinium iodide 
• 66-71-7 1,10-Phenanthroline 
• 1891-19-6 1,10-phenanthroline N-oxide 
• 31535-89-4 1-methyl-1,10-phenanthrolin-2(1H)-one 

Downstream Products

• 122768-45-0 2-Diphenylphosphanyl-[1,10]phenanthroline 
• 22426-17-1 2-phenoxy-1,10-phenanthroline 
• 29176-55-4 2,9-dichloro-[1,10]phenanthroline 
• 124318-70-3 2-(2',6'-Dimethoxyphenyl)-1,10-phenanthroline 
• 500711-43-3 2-{2,6-dimethoxy-4[(2-tetrahydropyranyloxy)methyl]phenyl}-1,10-phenanthroline 
• 498534-34-2 2-(2'-ethylsulfonylbenzyl)-1,10-phenanthroline 
• 77544-93-5 benzaldehyde (1,10-phenanthrolin-2-yl)hydrazone 
• 77553-79-8 benzaldehyde methyl(1,10-phenanthrolin-2-yl)hydrazone 

Relevant articles and documents

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Luminescent complexes of europium (III) with 2-(phenylethynyl)-1,10-phenanthroline: The role of the counterions

New antenna ligand, 2-(phenylethynyl)-1,10-phenanthroline (PEP), and its luminescent Eu(III) complexes, Eu(PEP)2Cl3 and Eu(PEP)2(NO3)3, are synthesized and characterized. The syn-thetic procedure applied is based on reacting of europium salts with ligand

Copper-Catalyzed Regioselective C-H Amination of Phenol Derivatives with Assistance of Phenanthroline-Based Bidentate Auxiliary

A copper-catalyzed regioselective direct amination of phenol derivatives with diarylamines via phenanthroline-based bidentate auxiliary-directed C-H cleavage has been developed. This reaction proceeds smoothly with only a copper salt and air as a terminal oxidant to produce the corresponding o-aminophenols in good yields. Moreover, the directing group can be easily attached, detached, and recycled. Additionally, preliminary computational studies of the reaction with DFT have also been performed.