163627-97-2

Upstream product

• 67-56-1 methanol 
• 39682-04-7 (3aR,5S,6R,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuran[2,3-d][1,3]dioxolane-5-carboxylic acid 

Downstream Products

• 217325-03-6 (1S,3R,4R,5S,6R,7R)-7-acetoxy-6-benzyloxy-5-benzyloxymethyl-4-benzyloxy-3-acetoxymethyl-2,8-dioxabicyclo[3.2.1]octane 
• 250584-41-9 (6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-benzyloxymethyl-6,7-O-isopropyl-α-D-galactofuranoside 
• 217325-05-8 ((2S,3R,4R,5S)-3-Benzyloxy-2-benzyloxymethyl-5-methoxy-4-methoxymethoxy-tetrahydro-furan-2-yl)-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol 
• 217325-00-3 methyl (methyl-3-O-benzyl-2-O-methoxymethyl-4-C-(hydroxy-(2,2-dimethyl[1,3]dioxolan-4-yl)methyl)-α-D-xylo/β-L-arabinofuranoside) uronate 
• 250584-40-8 (6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside 

Relevant academic research and scientific papers

A short synthesis of the bicyclic core of the zaragozic acids

A synthesis of the highly functionalized bicyclic core of the zaragozic acids is described, in which the key step involves the construction of the C4 quaternary carbon center by a CeCl3-promoted aldol reaction between the α- D-xylofuranuronic acid derivative 2 and D-(R)-glyceraldehyde acetonide.

Synthesis of polyhydroxylated 6-N-benzylpiperidin-2-ones. A novel access to 1,5-dideoxy-1,5-imino-D-xylitol

The synthesis of polyhydroxylated 6-N-benzylpiperidin-2-ones is described from the corresponding N-benzylaminoglycoside. These compounds are easily reduced to the differently protected 1,5-dideoxy-1,5-imino-D-xylitol.